15β-OH GA17, MeTMS
- Formula: C26H40O7Si
- Molecular weight: 492.6771
- IUPAC Standard InChI: InChI=1S/C26H40O7Si/c1-16-14-24-15-25(16,33-34(6,7)8)13-10-17(24)26(22(29)32-5)12-9-11-23(2,21(28)31-4)19(26)18(24)20(27)30-3/h17-19H,1,9-15H2,2-8H3/t17-,18-,19-,23-,24+,25+,26-/m0/s1
- IUPAC Standard InChIKey: JZPIBPZKAPRUHC-HCQYAENBSA-N
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: [14C] GA17 methyl ester TMS ether
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 2563. | Davis, Kobayashi, et al., 1999 | 25. m/0.2 mm/0.25 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | OV-1 | 2632. | Owen, Mander, et al., 1996 | Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | OV-1 | 2640. | Owen, Mander, et al., 1996 | Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Davis, Kobayashi, et al., 1999
Davis, G.; Kobayashi, M.; Phinney, B.O.; Lange, T.; Croker, S.J.; Gaskin, P.; MacMillan, J.,
Gibberellin biosynthesis in maize. Metabolic studies with GA15, GA24, GA25, GA7, and 2,3-dehydro-GA9,
Plant Physiol., 1999, 121, 3, 1037-1045, https://doi.org/10.1104/pp.121.3.1037
. [all data]
Owen, Mander, et al., 1996
Owen, D.J.; Mander, L.N.; Gaskin, P.; Macmillan, J.,
Synthesis and confirmation of structure of three 13,15β-dihydroxy C-20 gibberellins, GA100, GA101 and GA102 isolated from the seeds of Helianthus annuus L.,
Phytochemistry, 1996, 42, 4, 921-925, https://doi.org/10.1016/0031-9422(96)00045-3
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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