[14C1]GA3 methyl ester TMS ether

Formula: C₂₆H₄₀O₆Si₂
Molecular weight: 504.7632
IUPAC Standard InChI: InChI=1S/C26H40O6Si2/c1-16-14-24-15-25(16,32-34(7,8)9)12-10-17(24)26-13-11-18(31-33(4,5)6)23(2,22(28)30-26)20(26)19(24)21(27)29-3/h11,13,17-20H,1,10,12,14-15H2,2-9H3/t17-,18+,19-,20-,23-,24+,25+,26-/m0/s1
IUPAC Standard InChIKey: QJSHIGDRCGMRDL-GJUFPDMZSA-N
Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript.
Stereoisomers:
Other names: [14C] GA3 methyl ester TMS ether; [2H2]GA3, MeTMSi; [13C]GA3 methyl ester TMS ether
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Gas Chromatography

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type	Active phase	I	Reference	Comment
Capillary	OV-1	2685.	Davis, Kobayashi, et al., 1999	25. m/0.2 mm/0.25 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min)
Capillary	BP-1	2687.	MacMillan, Ward, et al., 1997	25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min)
Capillary	OV-1	2697.	Spray, Kobayashi, et al., 1996	25. m/0.2 mm/0.25 μm, He; Program: 60C(2min) => 10min/C => 150C => 3C/min => 300C

Column type	Active phase	I	Reference	Comment
Capillary	HP-1	2691.	Matheussen, Morgan, et al., 1991	12. m/0.2 mm/0.33 μm, He; Program: 60C(1min) => 15C/min => 200C => 5C/min => 270C
Capillary	HP-1	2703.	Matheussen, Morgan, et al., 1991	12. m/0.2 mm/0.33 μm, He; Program: 60C(1min) => 15C/min => 200C => 5C/min => 270C
Capillary	HP-1	2705.	Matheussen, Morgan, et al., 1991	12. m/0.2 mm/0.33 μm, He; Program: 60C(1min) => 15C/min => 200C => 5C/min => 270C
Capillary	HP-1	2709.	Matheussen, Morgan, et al., 1991	12. m/0.2 mm/0.33 μm, He; Program: 60C(1min) => 15C/min => 200C => 5C/min => 270C
Capillary	HP-1	2712.	Matheussen, Morgan, et al., 1991	12. m/0.2 mm/0.33 μm, He; Program: 60C(1min) => 15C/min => 200C => 5C/min => 270C

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Davis, Kobayashi, et al., 1999
Davis, G.; Kobayashi, M.; Phinney, B.O.; Lange, T.; Croker, S.J.; Gaskin, P.; MacMillan, J., Gibberellin biosynthesis in maize. Metabolic studies with GA₁₅, GA₂₄, GA₂₅, GA₇, and 2,3-dehydro-GA₉, Plant Physiol., 1999, 121, 3, 1037-1045, https://doi.org/10.1104/pp.121.3.1037 . [all data]

MacMillan, Ward, et al., 1997
MacMillan, J.; Ward, D.A.; Phillips, A.L.; Sánchez-Beltrán, M.J.; Gaskin, P.; Lange, T.; Hedden, P., Gibberellin biosynthesis from gibberellin A₁₂-aldehyde in endosperm and embryos of Marah macrocarpus, Plant Physiol., 1997, 113, 4, 1369-1377, https://doi.org/10.1104/pp.113.4.1369 . [all data]

Spray, Kobayashi, et al., 1996
Spray, C.R.; Kobayashi, M.; Suzuki, Y.; Phinney, B.O.; Gaskin, P.; MacMillan, J., The dwarf-1 (dl) mutant of Zea mays blocks three steps in the gibberellin-biosynthetic pathway, Proc. Nat. Acad. Sci. U.S.A., 1996, 93, 19, 10515-10518, https://doi.org/10.1073/pnas.93.19.10515 . [all data]

Matheussen, Morgan, et al., 1991
Matheussen, A.-M.; Morgan, P.W.; Frederiksen, R.A., Implication of gibberellins in head smut (Sporisorium reilianum) of Sorghum bicolor, Plant Physiol., 1991, 96, 2, 537-544, https://doi.org/10.1104/pp.96.2.537 . [all data]

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Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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