[2H2]GA1, MeTMS
- Formula: C26H42O6Si2
- Molecular weight: 506.7791
- IUPAC Standard InChI: InChI=1S/C26H42O6Si2/c1-16-14-24-15-25(16,32-34(7,8)9)12-10-17(24)26-13-11-18(31-33(4,5)6)23(2,22(28)30-26)20(26)19(24)21(27)29-3/h17-20H,1,10-15H2,2-9H3/t17-,18+,19-,20-,23-,24+,25+,26-/m0/s1
- IUPAC Standard InChIKey: UOYZRHLGPUDVGI-GJUFPDMZSA-N
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Stereoisomers:
- Other names: endo-GA1 methyl ester TMS ether; [2H2] GA1 MeTMSi; [14C]GA1, MeTMS; [13C]endo-GA1 methyl ester TMS ether; [2H2]GA1 methyl ester TMS ether
- Information on this page:
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2671. | Emery, Pearce, et al., 2001 | He; Column diameter: 0.25 mm; Phase thickness: 0.25 μm; Program: 60C(0.1min) => 20C/min => 200C => 5C/min => 300C |
| Capillary | SE-30 | 2647. | Odén, Wang, et al., 1995 | 25. m/0.25 mm/0.25 μm; Program: 80C(1min) => (20C/min) => 200C => (4C/min) => 250C |
| Capillary | Ultra-2 | 2724. | Zeevaart, Gage, et al., 1993 | 25. m/0.32 mm/0.52 μm; Program: not specified |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 2635. | Kobayashi, Gaskin, et al., 1994 | He; Column length: 25. m; Column diameter: 0.2 mm; Program: 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min) |
| Capillary | OV-1 | 2635. | Kobayashi, Gaskin, et al., 1994 | He; Column length: 25. m; Column diameter: 0.2 mm; Program: 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min) |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | SE-30 | 2670. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2670. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2670. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2674. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2674. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2674. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2676. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2676. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | SE-30 | 2676. | Wang, Little, et al., 1996 | 25. m/0.25 mm/0.25 μm; Program: 60 (2min) => 20C/min => 200C => 4C/min => 260C |
| Capillary | HP-1 | 2667. | Matheussen, Morgan, et al., 1991 | 12. m/0.2 mm/0.33 μm, He; Program: 60C(1min) => 15C/min => 200C => 5C/min => 270C |
| Capillary | HP-1 | 2668. | Matheussen, Morgan, et al., 1991 | 12. m/0.2 mm/0.33 μm, He; Program: 60C(1min) => 15C/min => 200C => 5C/min => 270C |
| Capillary | HP-1 | 2677. | Matheussen, Morgan, et al., 1991 | 12. m/0.2 mm/0.33 μm, He; Program: 60C(1min) => 15C/min => 200C => 5C/min => 270C |
| Capillary | HP-1 | 2678. | Matheussen, Morgan, et al., 1991 | 12. m/0.2 mm/0.33 μm, He; Program: 60C(1min) => 15C/min => 200C => 5C/min => 270C |
| Capillary | HP-1 | 2681. | Matheussen, Morgan, et al., 1991 | 12. m/0.2 mm/0.33 μm, He; Program: 60C(1min) => 15C/min => 200C => 5C/min => 270C |
| Capillary | HP-1 | 2682. | Matheussen, Morgan, et al., 1991 | 12. m/0.2 mm/0.33 μm, He; Program: 60C(1min) => 15C/min => 200C => 5C/min => 270C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Emery, Pearce, et al., 2001
Emery, R.J.N.; Pearce, D.W.; Pharis, R.P.; Reid, D.M.; Chinnappa, C.C.,
Stem elongation and gibberellins in alpine and prairie ecotypes of Stellaria longipes,
Plant Growth Regul., 2001, 35, 1, 17-29, https://doi.org/10.1023/A:1013823517189
. [all data]
Odén, Wang, et al., 1995
Odén, P.C.; Wang, Q.; Högberg, K.-A.; Werner, M.,
Transport and metabolism of gibberellins in relation to flower bud differentiation in Norway spruce (Picea abies),
Tree Physiol., 1995, 15, 7-8, 451-456, https://doi.org/10.1093/treephys/15.7-8.451
. [all data]
Zeevaart, Gage, et al., 1993
Zeevaart, J.A.D.; Gage, D.A.; Talon, M.,
Gibberellin A1 is required for stem elongation in spinach,
Proc. Natl. Acad. Sci. U.S.A, 1993, 90, 15, 7401-7405, https://doi.org/10.1073/pnas.90.15.7401
. [all data]
Kobayashi, Gaskin, et al., 1994
Kobayashi, M.; Gaskin, P.; Spray, C.R.; Phinney, B.O.; MacMillan, J.,
The metabolism of gibberellin A20 to gibberellin A1 by tall and dwarf mutants of Oryza sativa and Arabidopsis thaliana,
Plant Physiol., 1994, 106, 1367-1372. [all data]
Wang, Little, et al., 1996
Wang, Q.; Little, C.H.A.; Moritz, T.; Odén, P.C.,
Identification of endogenous gibberellins, and metabolism of tritiated and deuterated GA4, GA9, and GA20, in Scots pine (Pinus sylvestris) shoots,
Physiol. Plant., 1996, 97, 4, 764-771, https://doi.org/10.1111/j.1399-3054.1996.tb00542.x
. [all data]
Matheussen, Morgan, et al., 1991
Matheussen, A.-M.; Morgan, P.W.; Frederiksen, R.A.,
Implication of gibberellins in head smut (Sporisorium reilianum) of Sorghum bicolor,
Plant Physiol., 1991, 96, 2, 537-544, https://doi.org/10.1104/pp.96.2.537
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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