[13C]GA8 methyl ester TMS ether

Formula: C₂₉H₅₀O₇Si₃
Molecular weight: 594.9596
IUPAC Standard InChI: InChI=1S/C29H50O7Si3/c1-18-15-27-17-28(18,36-39(10,11)12)14-13-20(27)29-16-19(34-37(4,5)6)23(35-38(7,8)9)26(2,25(31)33-29)22(29)21(27)24(30)32-3/h19-23H,1,13-17H2,2-12H3/t19-,20+,21+,22+,23-,26-,27-,28-,29+/m1/s1
IUPAC Standard InChIKey: URXALWQXBINWJP-QKOPFLJYSA-N
Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript.
Species with the same structure:
- GA8-catabolite, MeTMS
Stereoisomers:
- GA56, MeTMSi
- GA8 methyl ester TMS ether
Other names: [2H2]GA8, MeTMS; [14C]GA8, MeTMS
Information on this page:
Options:
- Switch to calorie-based units

Gas Chromatography

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, custom temperature program

Column type	Active phase	I	Reference	Comment
Capillary	DB-1	2816.	Emery, Pearce, et al., 2001	He; Column diameter: 0.25 mm; Phase thickness: 0.25 μm; Program: 60C(0.1min) => 20C/min => 200C => 5C/min => 300C
Capillary	Ultra-2	2845.	Zeevaart, Gage, et al., 1993	25. m/0.32 mm/0.52 μm; Program: not specified

Van Den Dool and Kratz RI, non-polar column, custom temperature program

View large format table.

Column type	Active phase	I	Reference	Comment
Capillary	CP Sil 5 CB	2843.	Blake, Taylor, et al., 2002	25. m/0.25 mm/0.25 μm, He; Program: 60C (1min) => 20C/min => 170C => 4C/min => 290C
Capillary	OV-1	2820.	Spray, Kobayashi, et al., 1996	25. m/0.2 mm/0.25 μm, He; Program: 60C(2min) => 10min/C => 150C => 3C/min => 300C
Capillary	OV-1	2820.	Kobayashi, Gaskin, et al., 1994	He; Column length: 25. m; Column diameter: 0.2 mm; Program: 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min)

References

Go To: Top, Gas Chromatography, Notes

Emery, Pearce, et al., 2001
Emery, R.J.N.; Pearce, D.W.; Pharis, R.P.; Reid, D.M.; Chinnappa, C.C., Stem elongation and gibberellins in alpine and prairie ecotypes of Stellaria longipes, Plant Growth Regul., 2001, 35, 1, 17-29, https://doi.org/10.1023/A:1013823517189 . [all data]

Zeevaart, Gage, et al., 1993
Zeevaart, J.A.D.; Gage, D.A.; Talon, M., Gibberellin A₁ is required for stem elongation in spinach, Proc. Natl. Acad. Sci. U.S.A, 1993, 90, 15, 7401-7405, https://doi.org/10.1073/pnas.90.15.7401 . [all data]

Blake, Taylor, et al., 2002
Blake, P.S.; Taylor, J.M.; Finch-Savage, W.E., Identification of abscisic acid, indole-3-acetic acid, jasmonic acid, indole-3-acetonitrile, methyl jasmonate and gibberellins in developing, dormant and startified seeds of ash (Fraxinus excelsior), Plant Growth Regul., 2002, 37, 2, 119-125, https://doi.org/10.1023/A:1020504610172 . [all data]

Spray, Kobayashi, et al., 1996
Spray, C.R.; Kobayashi, M.; Suzuki, Y.; Phinney, B.O.; Gaskin, P.; MacMillan, J., The dwarf-1 (dl) mutant of Zea mays blocks three steps in the gibberellin-biosynthetic pathway, Proc. Nat. Acad. Sci. U.S.A., 1996, 93, 19, 10515-10518, https://doi.org/10.1073/pnas.93.19.10515 . [all data]

Kobayashi, Gaskin, et al., 1994
Kobayashi, M.; Gaskin, P.; Spray, C.R.; Phinney, B.O.; MacMillan, J., The metabolism of gibberellin A₂₀ to gibberellin A₁ by tall and dwarf mutants of Oryza sativa and Arabidopsis thaliana, Plant Physiol., 1994, 106, 1367-1372. [all data]

Notes

Go To: Top, Gas Chromatography, References

Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
Customer support for NIST Standard Reference Data products.