GA34 catabolite, methyl ester TMS ether
- Formula: C26H42O6Si2
- Molecular weight: 506.7791
- IUPAC Standard InChI: InChI=1S/C26H42O6Si2/c1-15-12-25-13-16(15)10-11-18(25)26-14-17(31-33(4,5)6)21(32-34(7,8)9)24(2,23(28)30-26)20(26)19(25)22(27)29-3/h16-21H,1,10-14H2,2-9H3/t16?,17-,18+,19+,20+,21-,24-,25-,26+/m1/s1
- IUPAC Standard InChIKey: MABXSEMQIJETIP-WKVIEWINSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: [13C]endo-GA34 methyl ester TMS ether; endo-GA34 methyl ester TMS ether; [13C] GA34 methyl ester TMS ether; [14C1]GA34 methyl ester TMS ether
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | BP-1 | 2659. | MacMillan, Ward, et al., 1997 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | OV-1 | 2670. | Kobayashi, Gaskin, et al., 1993 | 25. m/0.2 mm/0.25 μm; Program: 50C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | OV-1 | 2644. | Kobayashi, Gaskin, et al., 1993 | 25. m/0.2 mm/0.25 μm; Program: 50C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | OV-1 | 2642. | Kobayashi, Gaskin, et al., 1993 | 25. m/0.2 mm/0.25 μm; Program: 50C(2min) => 10C/min => 150C => 3C/min => 300C |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
MacMillan, Ward, et al., 1997
MacMillan, J.; Ward, D.A.; Phillips, A.L.; Sánchez-Beltrán, M.J.; Gaskin, P.; Lange, T.; Hedden, P.,
Gibberellin biosynthesis from gibberellin A12-aldehyde in endosperm and embryos of Marah macrocarpus,
Plant Physiol., 1997, 113, 4, 1369-1377, https://doi.org/10.1104/pp.113.4.1369
. [all data]
Kobayashi, Gaskin, et al., 1993
Kobayashi, M.; Gaskin, P.; Spray, C.R.; Suzuki, Y.; Phinney, B.O.; MacMillan, J.,
Metabolism and biological activity of Gibberellin A4 in vegetative shoots of Zea mays, Oryza sativa, and Arabidopsis thaliana,
Plant Physiol., 1993, 102, 379-386. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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