A-Arabinopyranose, TMS
- Formula: C17H42O5Si4
- Molecular weight: 438.8544
- IUPAC Standard InChI: InChI=1S/C17H42O5Si4/c1-23(2,3)19-14-13-18-17(22-26(10,11)12)16(21-25(7,8)9)15(14)20-24(4,5)6/h14-17H,13H2,1-12H3/t14-,15?,16+,17-/m0/s1
- IUPAC Standard InChIKey: KEOUSSOURMHEKN-CYBCNJLJSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- α-D-Xylopyranose, 4TMS derivative
- β-D-Xylopyranose, 4TMS derivative
- A-Lyxopyranose, TMS
- A-Ribopyranose, TMS
- B-Arabinopyranose, TMS
- B-Lyxopyranose, TMS
- B-Ribopyranose, TMS
- α-D(-)-Lyxose, pyranose, TMS
- β-D(-)-Lyxose, pyranose, TMS
- α-D-(-)-Ribopyranose, 4TMS derivative
- β-D-(-)-Ribopyranose, 4TMS derivative
- β-D-(+)-Xylopyranose, 4TMS derivative
- D-Arabinopyranose, 4TMS derivative (isomer 1)
- D-Arabinopyranose, 4TMS derivative (isomer 2)
- DL-Arabinopyranose, 4TMS derivative
- β-D(-)-Lyxopyranose, 4TMS derivative
- α-D-(-)-Lyxopyranose, 4TMS derivative
- Other names: α-D-Arabinopyranose, TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | SE-54 | 180. | 1601. | García-Raso, Martínez-Castro, et al., 1987 | Column length: 40. m; Column diameter: 0.18 mm |
| Capillary | SE-54 | 180. | 1601. | Paez, Martínez-Castro, et al., 1987 | Column length: 45. m; Column diameter: 0.18 mm |
Kovats' RI, polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | Carbowax 20M | 160. | 1524. | García-Raso, Martínez-Castro, et al., 1987 | Column length: 25. m; Column diameter: 0.22 mm |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
García-Raso, Martínez-Castro, et al., 1987
García-Raso, A.; Martínez-Castro, I.; Páez, M.I.; Sanz, J.; García-Raso, J.; Saura-Calixto, F.,
Gas Chromatographic Behaviour of Carbohydrate Trimethylsilyl Ethers. I. Aldopentoses,
J. Chromatogr., 1987, 398, 9-20, https://doi.org/10.1016/S0021-9673(01)96491-X
. [all data]
Paez, Martínez-Castro, et al., 1987
Paez, M.; Martínez-Castro, I.; Sanz, J.; Olano, A.; García-Raso, A.; Saura-Calixto, F.,
Identification of the components of aldoses in a tautomeric equilibrium mixture as their trimethylsilyl ethers by capillary cas chromatography,
Chromatographia, 1987, 23, 1, 43-46, https://doi.org/10.1007/BF02310417
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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