12β-OH-GA9 methyl ester TMS ether
- Formula: C23H34O5Si
- Molecular weight: 418.5986
- IUPAC Standard InChI: InChI=1S/C23H34O5Si/c1-13-11-22-12-14(13)15(28-29(4,5)6)10-16(22)23-9-7-8-21(2,20(25)27-23)18(23)17(22)19(24)26-3/h14-18H,1,7-12H2,2-6H3/t14?,15-,16-,17-,18-,21-,22+,23-/m0/s1
- IUPAC Standard InChIKey: KKEMDAAVLAIFTB-XXMNCVSDSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: [13C]GA69, MeTMS; GA9, 12-β-Hydroxy, methyl ester, TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 2493. | Davis, Kobayashi, et al., 1998 | 25. m/0.2 mm/0.25 μm, He; Program: 60C(2min) => 10min/C => 150C => 3C/min => 300C |
| Capillary | OV-1 | 2489. | Gaskin, Gilmour, et al., 1984 | He; Column length: 25. m; Column diameter: 0.2 mm; Program: 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min) |
| Capillary | OV-1 | 2489. | Gaskin, Hutchison, et al., 1984 | Program: not specified |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Davis, Kobayashi, et al., 1998
Davis, G.; Kobayashi, M.; Phinney, B.O.; MacMillan, J.; Gaskin, P.,
The Metabolism of GA9 in maize (ZEA mays),
Phytochemistry, 1998, 47, 4, 635-639, https://doi.org/10.1016/S0031-9422(97)87974-5
. [all data]
Gaskin, Gilmour, et al., 1984
Gaskin, P.; Gilmour, S.J.; Lenton, J.R.; MacMillan, J.; Sponsel, V.M.,
Endogenous gibberellins and kauranoids identified from developing and germinating barley grain,
J. Plant Growth Regul., 1984, 2, 1-4, 229-242, https://doi.org/10.1007/BF02042252
. [all data]
Gaskin, Hutchison, et al., 1984
Gaskin, P.; Hutchison, M.; Lewis, N.; MacMillan, J.; Phinney, B.O.,
Microbiological conversion of 12-oxygenated and other derivatives of ent-kaur-16-en-19-oic acid by Gibberella Fujikuroi, mutant B1-41a,
Phytochemistry, 1984, 23, 3, 559-564, https://doi.org/10.1016/S0031-9422(00)80380-5
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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