B-Fructofuranose, TMS
- Formula: C21H52O6Si5
- Molecular weight: 541.0615
- IUPAC Standard InChI: InChI=1S/C21H52O6Si5/c1-28(2,3)22-16-18-19(25-30(7,8)9)20(26-31(10,11)12)21(24-18,27-32(13,14)15)17-23-29(4,5)6/h18-20H,16-17H2,1-15H3/t18-,19-,20+,21+/m0/s1
- IUPAC Standard InChIKey: PLNWQGWZBNJIQM-UWHLTILDSA-N
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Stereoisomers:
- A-Fructofuranose, TMS
- α-Sorbose, TMS
- α-Allofuranose, TMS
- A-Psicofuranose, TMS
- A-Sorbofuranose, TMS
- A-Tagatofuranose, TMS
- B-Psicofuranose, TMS
- B-Sorbofuranose, TMS
- B-Tagatofuranose, TMS
- α-Mannofuranose, TMS
- α-Talofuranose, TMS
- β-Idofuranose, TMS
- β-Talofuranose, TMS
- D-(-)-Tagatofuranose, pentakis(trimethylsilyl) ether (isomer 1)
- D-(-)-Tagatofuranose, pentakis(trimethylsilyl) ether (isomer 2)
- D-Psicofuranose, pentakis(trimethylsilyl) ether (isomer 1)
- D-Psicofuranose, pentakis(trimethylsilyl) ether (isomer 2)
- L-(-)-Sorbofuranose, pentakis(trimethylsilyl) ether
- D-(-)-Fructofuranose, pentakis(trimethylsilyl) ether (isomer 1)
- D-(-)-Fructofuranose, pentakis(trimethylsilyl) ether (isomer 2)
- Other names: β-Fructose, TMS
- Information on this page:
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | OV-1 | 180. | 1857. | Garcia-Raso, Fernandez-Diaz, et al., 1989 | Column length: 25. m; Column diameter: 0.22 mm |
| Packed | SE-30 | 210. | 1859. | Saura-Calixto, Cañellas, et al., 1984 | N2, Supelcoport (80-100mesh); Column length: 3. m |
Kovats' RI, polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | FFAP | 170. | 1712. | Garcia-Raso, Fernandez-Diaz, et al., 1989 | Column length: 24. m; Column diameter: 0.22 mm |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Garcia-Raso, Fernandez-Diaz, et al., 1989
Garcia-Raso, A.; Fernandez-Diaz, M.; Paez, M.I.; Sanz, J.; Martinez-Castro, I.,
Gas Chromatographic Retention of Carbohydrate Trimethylsilyl Ethers. III. Ketohexoses,
J. Chromatogr., 1989, 471, 205-216, https://doi.org/10.1016/S0021-9673(00)94168-2
. [all data]
Saura-Calixto, Cañellas, et al., 1984
Saura-Calixto, F.; Cañellas, J.; García-Raso, A.,
Gas chromatograph analysis of surgars and sugar-alcohols in the mesocarp, endocarp, and kernel of almond fruit,
J. Agric. Food Chem., 1984, 32, 5, 1018-1020, https://doi.org/10.1021/jf00125a017
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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