Cl3PS+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 70270 ± 320 gas Cox, Evans, et al., 1972
Bunzli, Frost, et al., 1972
Vovna, Lopatin, et al., 1973

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 46230 ± 320 gas Cox, Evans, et al., 1972
Bunzli, Frost, et al., 1972
Vovna, Lopatin, et al., 1973
Berkosky, Ellison, et al., 1973

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 39620 ± 320 gas Cox, Evans, et al., 1972
Bunzli, Frost, et al., 1972
Vovna, Lopatin, et al., 1973
Berkosky, Ellison, et al., 1973

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 30340 ± 320 gas Cox, Evans, et al., 1972
Bunzli, Frost, et al., 1972
Vovna, Lopatin, et al., 1973
Berkosky, Ellison, et al., 1973

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 24400 T gas Cox, Evans, et al., 1972
Bunzli, Frost, et al., 1972
Vovna, Lopatin, et al., 1973
Berkosky, Ellison, et al., 1973

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 22400 T gas Cox, Evans, et al., 1972
Bunzli, Frost, et al., 1972
Vovna, Lopatin, et al., 1973
Berkosky, Ellison, et al., 1973

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 8390 ± 320 gas Cox, Evans, et al., 1972
Bunzli, Frost, et al., 1972
Vovna, Lopatin, et al., 1973
Berkosky, Ellison, et al., 1973

Additional references: Jacox, 1994, page 299

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox, Evans, et al., 1972
Cox, P.A.; Evans, S.; Orchard, A.F.; Richardson, N.V.; Roberts, P.J., Simple quantitative molecular orbital methods used in connection with photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1972, 54, 26. [all data]

Bunzli, Frost, et al., 1972
Bunzli, J.C.; Frost, D.C.; McDowell, C.A., Photoelectron spectra of phosphoryl and thiophosphoryl chlorides and bromides, J. Electron Spectrosc. Relat. Phenom., 1972, 1, 5, 481, https://doi.org/10.1016/0368-2048(72)80018-5 . [all data]

Vovna, Lopatin, et al., 1973
Vovna, V.I.; Lopatin, S.N.; Pettsold, R.; Vilesov, F.I.; Akopyan, M.E., Opt. Spektrosc., 1973, 34, 868. [all data]

Berkosky, Ellison, et al., 1973
Berkosky, J.L.; Ellison, F.O.; Lee, T.H.; Rabalais, J.W., Model for calculating spin-orbit interactions with applications to photoelectron spectroscopy, J. Chem. Phys., 1973, 59, 5342. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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