F3PS+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 72450 ± 320 gas Elbel and Dieck, 1976

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 70300 T gas Elbel and Dieck, 1976

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 60110 ± 500 gas Elbel and Dieck, 1976

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 56160 ± 320 gas Elbel and Dieck, 1976

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 46960 ± 500 gas Elbel and Dieck, 1976

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 42840 ± 320 gas Elbel and Dieck, 1976

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 27350 ± 320 gas Elbel and Dieck, 1976

Additional references: Jacox, 1994, page 299

Notes

TTentative assignment or approximate value
xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Elbel and Dieck, 1976
Elbel, S.; Dieck, H.t., Photoelectron spectra of group 5 compounds. Part IV. A study of the E-X bond in R3EX compounds (R = Me or F; E = N or P; X = O or S), J. Chem. Soc. Dalton Trans., 1976, 1757. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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