Hexamethyldisilazane
- Formula: C6H19NSi2
- Molecular weight: 161.3928
- IUPAC Standard InChI: InChI=1S/C6H19NSi2/c1-8(2,3)7-9(4,5)6/h7H,1-6H3
- IUPAC Standard InChIKey: FFUAGWLWBBFQJT-UHFFFAOYSA-N
- CAS Registry Number: 999-97-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Other names: Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-; Disilazane, 1,1,1,3,3,3-hexamethyl-; Bis(trimethylsilyl)amine; 1,1,1,3,3,3-Hexamethyldisilazane; ((CH3)3Si)2NH; HMDS; OAP; Trimethyl-N-(trimethylsilyl)silanamine; 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine; NSC 93895; SZ 6079; TSL 8802
- Information on this page:
- Other data available:
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tboil | 399. | K | N/A | Farchan Laboratories, 1990 | BS |
| Tboil | 399. | K | N/A | PCR Inc., 1990 | BS |
| Tboil | 397.2 | K | N/A | Myers and Clever, 1969 | Uncertainty assigned by TRC = 0.6 K; TRC |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔvapH° | 10.1 ± 0.2 | kcal/mol | C | Voronkov, Klyuchnikov, et al., 1991 | AC |
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 8.60 | 344. | Ditsent, Skorokhodov, et al., 1972 | Based on data from 294. to 395. K.; AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Farchan Laboratories, 1990
Farchan Laboratories,
Research Chemicals Catalog, Farchan Laboratories, Gainesville, FL, 1990, 91. [all data]
PCR Inc., 1990
PCR Inc.,
Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]
Myers and Clever, 1969
Myers, R.S.; Clever, H.L.,
Surface Tension of Octamethylcyclotetrasiloxane and Hexamethyldisilazane and Their Solutions with Carbon Tetrachloride and n-Hexadecane,
J. Chem. Eng. Data, 1969, 14, 161-164. [all data]
Voronkov, Klyuchnikov, et al., 1991
Voronkov, M.G.; Klyuchnikov, V.A.; Marenkova, L.I.; Danilova, T.F.; Shvets, G.N.; Tsvetnitskaya, S.I.; Khudobin, Yu.I.,
Thermochemistry of organosilicon compounds,
Journal of Organometallic Chemistry, 1991, 406, 1-2, 99-104, https://doi.org/10.1016/0022-328X(91)83175-4
. [all data]
Ditsent, Skorokhodov, et al., 1972
Ditsent, V.E.; Skorokhodov, I.I.; Terent'eva, N.A.; Zolotareva, M.N.,
Zh. Fiz. Khim., 1972, 46, 7, 1888. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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