Malic acid, 3TBDMS derivative

• Formula: C₂₂H₄₈O₅Si₃
• Molecular weight: 476.8700
• IUPAC Standard InChI: InChI=1S/C22H48O5Si3/c1-20(2,3)28(10,11)25-17(19(24)27-30(14,15)22(7,8)9)16-18(23)26-29(12,13)21(4,5)6/h17H,16H2,1-15H3 Copy

  
• IUPAC Standard InChIKey: LGKDLSNIOMYKSN-UHFFFAOYSA-N Copy
• CAS Registry Number: 99461-86-6
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Butanedioic acid, 2-[(tert-butyldimethylsilyl)oxy]-, bis(tert-butyldimethylsilyl) ester; DL-Malic acid, O-tert-butyldimethylsilyl-, bis(tert-butyldimethylsilyl) ester; Malic acid, tris-TBDMS; Malic acid, TBDMS; Malic acid, DMTBS
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• Information on this page:
  • Mass spectrum (electron ionization)
  • Gas Chromatography
  • References
  • Notes
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Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Normal alkane RI, non-polar column, temperature ramp

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Tret'yakov, 2007
Tret'yakov, K.V., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]

Paik, Lee, et al., 2005
Paik, M.-J.; Lee, H.-J.; Kim, K.-R., Simultaneous retention index analysis of urinary amino acids and carboxylic acids for graphic recognition of abnormal state, J. Chromatogr. B, 2005, 821, 1, 94-104, https://doi.org/10.1016/j.jchromb.2005.04.011 . [all data]

Kim, Kim, et al., 1990
Kim, K.-R.; Kim, J.-H.; Park, H.-K., Trace analysis as TBDMS derivatives of organic acids in aqueous samples, J. Korean Chem. Soc., 1990, 34, 4, 352-359. [all data]

Kim, Hahn, et al., 1989
Kim, K.R.; Hahn, M.K.; Zlatkis, A.; Horning, E.C.; Middleditch, B.S., Simultaneous gas chromatography of volatile and nonvolatile carboxylic acids as tert.-butyldimethylsilyl derivatives, J. Chromatogr., 1989, 468, 289-301, https://doi.org/10.1016/S0021-9673(00)96323-4 . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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