Benzene, (trichloromethyl)-

• Formula: C₇H₅Cl₃
• Molecular weight: 195.474
• IUPAC Standard InChI: InChI=1S/C7H5Cl3/c8-7(9,10)6-4-2-1-3-5-6/h1-5H Copy

  
• IUPAC Standard InChIKey: XEMRAKSQROQPBR-UHFFFAOYSA-N Copy
• CAS Registry Number: 98-07-7
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Species with the same structure:
  • trichlorotoluene
• Other names: Toluene, α,α,α-trichloro-; Trichlorotoluene; (Trichloromethyl)benzene; Benzenyl trichloride; Benzotrichloride; Benzyl trichloride; Benzylidyne chloride; Phenylchloroform; Phenyltrichloromethane; Toluene trichloride; Trichlorophenylmethane; 1-(Trichloromethyl)benzene; Benzenyl chloride; α,α,α-Trichlorotoluene; ω,ω,ω-Trichlorotoluene; Chlorure de benzenyle; Trichloormethylbenzeen; Trichlormethylbenzol; Triclorometilbenzene; Benzoic trichloride; Rcra waste number U023; UN 2226; α,α,α-Trichloromethylbenzene; NSC 14663
• Information on this page:
  • Phase change data
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Gas Chromatography
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Enthalpy of fusion

Enthalpy of phase transition

Entropy of phase transition

References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Goates, Boerio-Goates, et al., 1987
Goates, J.R.; Boerio-Goates, J.; Goates, S.R.; Ott, J.B., (Solid + Liquid) Phase Equilibria for (N,N-Dimethylacetamide + Tetra- chloromethane): Enthalpies of Meltingof Pure Compounds and Enthalpies for Formation of Moelcular Addition Compounds from Phase Eq, J. Chem. Thermodyn., 1987, 19, 103. [all data]

Altschul and Von Schneider, 1895
Altschul, M.; Von Schneider, B., Freezing points of some organic fluids, Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1895, 16, 24. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Ahmed and Eades, 1972
Ahmed, A.M.I.; Eades, R.G., Proton magnetic relaxation in toluene and some derivatives, J. Chem. Soc., Faraday Trans. 2, 1972, 68, 1623, https://doi.org/10.1039/f29726801623 . [all data]

Goates, Boerio-Goates, et al., 1987, 2
Goates, J.R.; Boerio-Goates, J.; Goates, S.R.; Ott, J.B., (Solid + liquid) phase equilibria for (N,N-dimethylacetamide + tetrachloromethane): enthalpies of melting of pure components and enthalpies for formation of molecular addition compounds from phase equilibria, J. Chem. Thermodynam., 1987, 19, 103-107. [all data]

Notes

Go To: Top, Phase change data, References

• Symbols used in this document:
  

  Tboil	Boiling point
  Tfus	Fusion (melting) point
  ΔHtrs	Enthalpy of phase transition
  ΔStrs	Entropy of phase transition
  ΔfusH	Enthalpy of fusion
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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