Eugenol
- Formula: C10H12O2
- Molecular weight: 164.2011
- IUPAC Standard InChI: InChI=1S/C10H12O2/c1-3-4-8-5-6-9(11)10(7-8)12-2/h3,5-7,11H,1,4H2,2H3
- IUPAC Standard InChIKey: RRAFCDWBNXTKKO-UHFFFAOYSA-N
- CAS Registry Number: 97-53-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Phenol, 2-methoxy-4-(2-propenyl)-; Phenol, 4-allyl-2-methoxy-; p-Allylguaiacol; p-Eugenol; Caryophyllic acid; Engenol; Eugenic acid; 2-Methoxy-1-hydroxy-4-allylbenzene; 2-Methoxy-4-allylphenol; 4-Allyl-2-methoxyphenol; 4-Allylguaiacol; 4-Hydroxy-3-methoxyallylbenzene; NCI-C50453; 1-Hydroxy-2-methoxy-4-allylbenzene; 1-Hydroxy-2-methoxy-4-prop-2-enylbenzene; 2-Methoxy-4-(2-propenyl)phenol; 2-Methoxy-4-prop-2-enylphenol; 4-Allyl-1-hydroxy-2-methoxybenzene; 4-Allylcatechol-2-methyl ether; 1,3,4-Eugenol; FA 100; FEMA No. 2467; 2-Metoksy-4-allilofenol; 2-Hydroxy-5-allylanisole; Allylguaiacol; 4-(2-Propenyl)-2-methoxyphenol; NSC 209525; Phenol, 2-methoxy-4-(2-propen-1-yl)-; 4-allyl-2-methoxyphenol (eugenol); 4-(2-Propenyl)-2-methoxyphenol (eugenol); 4-Allyl-2-rnethoxyphenol (eugenol); Eugenol (2-Methoxy-4-(2-propenyl)phenol)
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Kovats' RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5MS | CP Sil 8 CB | CP Sil 8 CB | DB-5 | CP Sil 8 CB |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | He | H2 | H2 | He | H2 |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 50. | 50. | 60. | 50. |
| Tend (C) | 280. | 220. | 220. | 300. | 220. |
| Heat rate (K/min) | 2. | 3. | 3. | 5. | 3. |
| Initial hold (min) | 8. | 2. | 2. | 2. | |
| Final hold (min) | 30. | ||||
| I | 1373. | 1368. | 1367. | 1348. | 1342. |
| Reference | Hazzit, Baaliouamer, et al., 2006 | Tayoub, Schwob, et al., 2006 | Tayoub, Schwob, et al., 2006, 2 | Santos, Lopes, et al., 2004 | Schwob, Bessiere, et al., 2004 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | HP-5 | DB-5 | SE-30 | HP-5 |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | He | He | He | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 1. | 0.25 | 0.25 | 0.25 | |
| Tstart (C) | 40. | 60. | 50. | 60. | 60. |
| Tend (C) | 250. | 280. | 250. | 240. | 200. |
| Heat rate (K/min) | 5. | 3. | 0.5 | 4. | 4. |
| Initial hold (min) | 1. | 5. | 1. | ||
| Final hold (min) | 10. | 15. | |||
| I | 1378. | 1348. | 1356. | 1327. | 1358. |
| Reference | Bouzouita, Kachouri, et al., 2003 | Özcan, Tzakou, et al., 2003 | Viña and Murillo, 2003 | Juliani, Koroch, et al., 2002 | Juliani and Simon, 2002 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | BP-1 | BP-1 | HP-1 | BP-1 | DB-1 |
| Column length (m) | 25. | 30. | 50. | 25. | 30. |
| Carrier gas | N2 | N2 | He | N2 | He |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.32 | 0.25 | 0.55 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 60. | 100. | 60. | 40. |
| Tend (C) | 220. | 220. | 250. | 220. | 260. |
| Heat rate (K/min) | 5. | 5. | 5. | 5. | 2. |
| Initial hold (min) | 7. | 5. | |||
| Final hold (min) | 15. | 13. | 15. | 20. | |
| I | 1339. | 1330. | 1337. | 1340. | 1330. |
| Reference | Raina, Srivastava, et al., 2002 | Shawl, Srivastava, et al., 2002 | Raina, Srivastava, et al., 2001 | Raina, Srivastava, et al., 2001, 2 | Senatore and Rigano, 2001 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | SE-54 | DB-5 | CP Sil 5 CB | DB-5 |
| Column length (m) | 30. | 30. | 30. | 25. | 30. |
| Carrier gas | He | He | He | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.26 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | ||
| Tstart (C) | 60. | 60. | 60. | 60. | 60. |
| Tend (C) | 280. | 246. | 180. | 280. | 240. |
| Heat rate (K/min) | 3. | 3. | 2. | 5. | 3. |
| Initial hold (min) | |||||
| Final hold (min) | |||||
| I | 1354. | 1356. | 1362. | 1340. | 1358. |
| Reference | Tzakou and Couladis, 2001 | Adams, 2000 | Rao, Rout, et al., 2000 | Kaul, Gujral, et al., 1999 | da Silva, Andrade, et al., 1999 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-1 | SPB-1 | DB-5 | DB-1 | DB-1 |
| Column length (m) | 30. | 30. | 30. | 60. | 60. |
| Carrier gas | He | He | He | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.23 | 0.32 | 0.25 | 0.32 | 0.32 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
| Tstart (C) | 50. | 60. | 60. | 30. | 30. |
| Tend (C) | 200. | 250. | 240. | 210. | 210. |
| Heat rate (K/min) | 3. | 5. | 3. | 2. | 2. |
| Initial hold (min) | 2. | 4. | 4. | ||
| Final hold (min) | 5. | ||||
| I | 1337. | 1354. | 1356. | 1325. | 1326. |
| Reference | Fiorini, Fourasté, et al., 1997 | Jayaprakasha, Jaganmohan Rao, et al., 1997 | Tellez, Estell, et al., 1997 | Takeoka, Buttery, et al., 1992 | Takeoka, Buttery, et al., 1992 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | BP-1 | OV-101 | SF96+Igepal | OV-101 | OV-101 |
| Column length (m) | 50. | 100. | 127. | 70. | 70. |
| Carrier gas | H2 | H2 | N2 | N2 | |
| Substrate | |||||
| Column diameter (mm) | 0.33 | 0.3 | 0.75 | 0.28 | 0.28 |
| Phase thickness (μm) | 0.15 | ||||
| Tstart (C) | 65. | 90. | 70. | 80. | 80. |
| Tend (C) | 220. | 220. | 190. | 200. | 200. |
| Heat rate (K/min) | 5. | 2. | 1. | 2. | 2. |
| Initial hold (min) | 2. | ||||
| Final hold (min) | |||||
| I | 1338. | 1354. | 1359. | 1347. | 1347. |
| Reference | Ekundayo, Laakso, et al., 1988 | Gaydou, Randriamiharisoa, et al., 1986 | Palma-Fleming and Kepner, 1983 | Yamaguchi and Shibamoto, 1981 | Yamaguchi and Shibamoto, 1981 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary |
|---|---|---|
| Active phase | OV-101 | OV-101 |
| Column length (m) | 70. | 70. |
| Carrier gas | N2 | N2 |
| Substrate | ||
| Column diameter (mm) | 0.28 | 0.28 |
| Phase thickness (μm) | ||
| Tstart (C) | 80. | 80. |
| Tend (C) | 200. | 200. |
| Heat rate (K/min) | 2. | 2. |
| Initial hold (min) | ||
| Final hold (min) | ||
| I | 1347. | 1347. |
| Reference | Yamaguchi and Shibamoto, 1979 | Yamaguchi and Shibamoto, 1979 |
| Comment | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hazzit, Baaliouamer, et al., 2006
Hazzit, M.; Baaliouamer, A.; Faleiro, M.L.; Miguel, M.G.,
Composition of the Essential Oils of Thymus and Origanum Species from Algeria and Their Antioxidant and Antimicrobial Activities,
J. Agric. Food Chem., 2006, 54, 17, 6314-6321, https://doi.org/10.1021/jf0606104
. [all data]
Tayoub, Schwob, et al., 2006
Tayoub, G.; Schwob, I.; Bessiere, J.-M.; Masotti, V.; Rabier, J.; Ruzzier, M.; Viano, J.,
Composition of volatile oils of Styrax (Styrax officinalis L.) leaves at different phenological stages,
Biochem. Syst. Ecol., 2006, 34, 9, 705-709, https://doi.org/10.1016/j.bse.2006.05.008
. [all data]
Tayoub, Schwob, et al., 2006, 2
Tayoub, G.; Schwob, I.; Bessière, J.-M.; Rabier, J.; Masotti, V.; J.; M.; Girard, G.; Viano, J.,
Essential oil composition of leaf, flower and stem of Styrax (Styrax officinalis L.) from south-eastern France,
Flavour Fragr. J., 2006, 21, 5, 809-812, https://doi.org/10.1002/ffj.1731
. [all data]
Santos, Lopes, et al., 2004
Santos, A.P.; Lopes, M.C.; Limberger, R.P.; Apel, M.A.; Henriques, A.T.; Moreno, P.R.H.,
Analysis of the volatile oil from Pilocarpus pennatifolius Lemmaire (Rutaceae) leaves by GC-MS,
Flavour Fragr. J., 2004, 19, 4, 325-326, https://doi.org/10.1002/ffj.1306
. [all data]
Schwob, Bessiere, et al., 2004
Schwob, I.; Bessiere, J.-M.; Masotti, V.; Viano, J.,
Changes in essential oil composition in Saint John's wort (Hypericum perforatum L.) aerial parts during its phenological cycle,
Biochem. Syst. Ecol., 2004, 32, 8, 735-745, https://doi.org/10.1016/j.bse.2003.12.005
. [all data]
Bouzouita, Kachouri, et al., 2003
Bouzouita, N.; Kachouri, F.; Hamdi, M.; Chaabouni, M.M.,
Antimicrobial activity of essential oils from Tunisian aromatic plants,
Flavour Fragr. J., 2003, 18, 5, 380-383, https://doi.org/10.1002/ffj.1200
. [all data]
Özcan, Tzakou, et al., 2003
Özcan, M.; Tzakou, O.; Couladis, M.,
Essential oil composition of Turkish herbal tea (Salvia aucheri Bentham var. canescens Boiss. Heldr.),
Flavour Fragr. J., 2003, 18, 4, 325-327, https://doi.org/10.1002/ffj.1229
. [all data]
Viña and Murillo, 2003
Viña, A.; Murillo, E.,
Essential oil composition from twelve varieties of basil (Ocimum spp) grown in Columbia,
J. Braz. Chem. Soc., 2003, 14, 5, 744-749, https://doi.org/10.1590/S0103-50532003000500008
. [all data]
Juliani, Koroch, et al., 2002
Juliani, H.R., Jr.; Koroch, A.R.; Juliani, H.R.; Trippi, V.S.; Zygadlo, J.A.,
Intraespecific variation in leafoils of Lippia junelliana (mold.) tronc,
Biochem. Syst. Ecol., 2002, 30, 2, 163-170, https://doi.org/10.1016/S0305-1978(01)00067-9
. [all data]
Juliani and Simon, 2002
Juliani, H.R.; Simon, J.E.,
Antioxidant acitivity of basil
in Trends in new crops and new uses, Janick,J.; Whipkey,A., ed(s)., ASHA Press, Alexandria, Va, 2002, 575-579. [all data]
Raina, Srivastava, et al., 2002
Raina, V.K.; Srivastava, S.K.; Syamasunder, K.V.,
The essential oil of 'greater galangal' [Alpinia galanga (L.) Willd.] from the lower Himalayan region of India,
Flavour Fragr. J., 2002, 17, 5, 358-360, https://doi.org/10.1002/ffj.1105
. [all data]
Shawl, Srivastava, et al., 2002
Shawl, A.S.; Srivastava, S.K.; Syamasundar, K.V.; Tripathi, S.; Raina, V.K.,
Essential oil composition of Achillea millefolium L. growing wild in Kashmir, India,
Flavour Fragr. J., 2002, 17, 3, 165-168, https://doi.org/10.1002/ffj.1074
. [all data]
Raina, Srivastava, et al., 2001
Raina, V.K.; Srivastava, S.K.; Aggarwal, K.K.; Syamasundar, K.V.; Kumar, S.,
Essential oil composition of Syzygium aromaticum leaf from Little Andaman, India,
Flavour Fragr. J., 2001, 16, 5, 334-336, https://doi.org/10.1002/ffj.1005
. [all data]
Raina, Srivastava, et al., 2001, 2
Raina, V.K.; Srivastava, S.K.; Aggarwal, K.K.; Ramesh, S.; Kumar, S.,
Essential oil composition of Cinnamomum zeylanicum Blume leaves from Little Andaman, India,
Flavour Fragr. J., 2001, 16, 5, 374-376, https://doi.org/10.1002/ffj.1016
. [all data]
Senatore and Rigano, 2001
Senatore, F.; Rigano, D.,
Essential oil of two Lippia spp. (Verbenaceae) growing wild in Guatemala,
Flavour Fragr. J., 2001, 16, 3, 169-171, https://doi.org/10.1002/ffj.972
. [all data]
Tzakou and Couladis, 2001
Tzakou, O.; Couladis, M.,
The essential oil of Micromeria graeca (L.) Bentham et Reichenb. growing in Greece,
Flavour Fragr. J., 2001, 16, 2, 107-109, https://doi.org/10.1002/ffj.955
. [all data]
Adams, 2000
Adams, R.P.,
Systematics of smooth leaf margin Juniperus of the western hemisphere based on leaf essential oils and RAPD DNA fingerprinting,
Biochem. Syst. Ecol., 2000, 28, 2, 149-162, https://doi.org/10.1016/S0305-1978(99)00047-2
. [all data]
Rao, Rout, et al., 2000
Rao, Y.R.; Rout, P.K.; Jena, K.S.; Sahu, S.B.,
Composition of essential oil of citronella (Cymbopogon winterianus jowitt) grown in coastal Orissa,
Fafai J., 2000, 2, 4, 29-31. [all data]
Kaul, Gujral, et al., 1999
Kaul, V.K.; Gujral, R.K.; Singh, B.,
Volatile constituents of the essential oil of flowers of Rosa brunonii Lindl,
Flavour Fragr. J., 1999, 14, 1, 9-11, https://doi.org/10.1002/(SICI)1099-1026(199901/02)14:1<9::AID-FFJ761>3.0.CO;2-C
. [all data]
da Silva, Andrade, et al., 1999
da Silva, M.H.L.; Andrade, E.H.A.; Zoghbi, M.G.B.; Luz, A.I.R.; da Silva, J.D.; Maia, J.G.S.,
The essential oils of Lantana camara L. occurring in North Brazil,
Flavour Fragr. J., 1999, 14, 4, 208-210, https://doi.org/10.1002/(SICI)1099-1026(199907/08)14:4<208::AID-FFJ811>3.0.CO;2-F
. [all data]
Fiorini, Fourasté, et al., 1997
Fiorini, C.; Fourasté, I.; David, B.; Bessière, J.M.,
Composition of the flower, leaf, and stem essential oils from Laurus nobilis L.,
Flavour Fragr. J., 1997, 12, 2, 91-93, https://doi.org/10.1002/(SICI)1099-1026(199703)12:2<91::AID-FFJ623>3.0.CO;2-3
. [all data]
Jayaprakasha, Jaganmohan Rao, et al., 1997
Jayaprakasha, G.K.; Jaganmohan Rao, L.; Sakariah, K.K.,
Chemical composition of the volatile oil from the fruits of Cinnamomum zeylanicum blume,
Flavour Fragr. J., 1997, 12, 5, 331-333, https://doi.org/10.1002/(SICI)1099-1026(199709/10)12:5<331::AID-FFJ663>3.0.CO;2-X
. [all data]
Tellez, Estell, et al., 1997
Tellez, M.R.; Estell, R.E.; Fredrickson, E.L.; Havstad, K.M.,
Essential oil of Dyssodia acerosa DC.,
J. Agric. Food Chem., 1997, 45, 8, 3276-3278, https://doi.org/10.1021/jf9701502
. [all data]
Takeoka, Buttery, et al., 1992
Takeoka, G.R.; Buttery, R.G.; Flath, R.A.,
Volatile constituents of Asian pear (Pyrus serotina),
J. Agric. Food Chem., 1992, 40, 10, 1925-1929, https://doi.org/10.1021/jf00022a040
. [all data]
Ekundayo, Laakso, et al., 1988
Ekundayo, O.; Laakso, I.; Adegbola, R.-M.; Oguntimein, B.; Sofowora, A.; Hiltunen, R.,
Essential oil constituents of Ashanti pepper (Piper guineense) fruits (berries),
J. Agric. Food Chem., 1988, 36, 5, 880-882, https://doi.org/10.1021/jf00083a001
. [all data]
Gaydou, Randriamiharisoa, et al., 1986
Gaydou, E.M.; Randriamiharisoa, R.; Bianchini, J.-P.,
Composition of the essential oil of ylang-ylang (Canaga odorata Hook Fil. et Thomson forma genuina) from Madagascar,
J. Agric. Food Chem., 1986, 34, 3, 481-487, https://doi.org/10.1021/jf00069a028
. [all data]
Palma-Fleming and Kepner, 1983
Palma-Fleming, H.A.; Kepner, R.E.,
Volatile components of California live oak, Quercus agrifolia,
Phytochemistry, 1983, 22, 6, 1503-1505, https://doi.org/10.1016/S0031-9422(00)84047-9
. [all data]
Yamaguchi and Shibamoto, 1981
Yamaguchi, K.; Shibamoto, T.,
Volatile constituents of green tea, Gyokuro (Camellia sinensis L. var Yabukita),
J. Agric. Food Chem., 1981, 29, 2, 366-370, https://doi.org/10.1021/jf00104a035
. [all data]
Yamaguchi and Shibamoto, 1979
Yamaguchi, K.; Shibamoto, T.,
Volatile constituents of Castanopsis flower,
J. Agric. Food Chem., 1979, 27, 4, 847-850, https://doi.org/10.1021/jf60224a025
. [all data]
Notes
Go To: Top, Kovats' RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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