Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Perfluoro(methylcyclohexane) anion


Ion clustering data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Perfluoro(methylcyclohexane) anion + Methyl Alcohol = (Perfluoro(methylcyclohexane) anion bullet Methyl Alcohol)

By formula: C7F14- + CH4O = (C7F14- bullet CH4O)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
27.308.PHPMSKnighton, Zook, et al., 1990gas phase; M

Perfluoro(methylcyclohexane) anion + Dimethyl Sulfoxide = (Perfluoro(methylcyclohexane) anion bullet Dimethyl Sulfoxide)

By formula: C7F14- + C2H6OS = (C7F14- bullet C2H6OS)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
32.308.PHPMSKnighton, Zook, et al., 1990gas phase; M

Perfluoro(methylcyclohexane) anion + Benzene, nitro- = (Perfluoro(methylcyclohexane) anion bullet Benzene, nitro-)

By formula: C7F14- + C6H5NO2 = (C7F14- bullet C6H5NO2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
28.300.PHPMSChowdhury and Kebarle, 1986gas phase; M

Perfluoro(methylcyclohexane) anion + Benzene, nitro- = C13H5F14NO2-

By formula: C7F14- + C6H5NO2 = C13H5F14NO2-

Quantity Value Units Method Reference Comment
Deltar28. ± 4.2kJ/molIMREChowdhury and Kebarle, 1986gas phase; B

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Knighton, Zook, et al., 1990
Knighton, W.B.; Zook, D.R.; Grimsrud, E.P., Cluster-Assisted Decomposition Reactions of the Molecular Anions of SF6 and C7F14, J. Am. Soc. Mass Spectrom., 1990, 1, 5, 372, https://doi.org/10.1016/1044-0305(90)85017-G . [all data]

Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P., Role of Binding Energies in A-.B and A.B- Complexes in the Kinetics of Gas Phase Electron Transfer Reactions:A- + B = A + B- Involving Perfluoro Compounds: SF6, C6F11CF3, J. Chem. Phys., 1986, 85, 9, 4989, https://doi.org/10.1063/1.451687 . [all data]


Notes

Go To: Top, Ion clustering data, References