Soman

• Formula: C₇H₁₆FO₂P
• Molecular weight: 182.1729
• IUPAC Standard InChI: InChI=1S/C7H16FO2P/c1-6(7(2,3)4)10-11(5,8)9/h6H,1-5H3 Copy

  
• IUPAC Standard InChIKey: GRXKLBBBQUKJJZ-UHFFFAOYSA-N Copy
• CAS Registry Number: 96-64-0
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Species with the same structure:
  • pinacolyl methylphosphonofluoridate, diastereomer 1
• Other names: Phosphonofluoridic acid, methyl-, 1,2,2-trimethylpropyl ester; 1,2,2-Trimethylpropoxyfluorophosphine oxide; O-Pinacolyl methylphosphonofluoridate; GD; Methyl pinacolyl phosphonofluoridate; Methyl pinacolyloxy phosphorylfluoride; Phosphine oxide, fluoromethyl(1,2,2-trimethylpropoxy)-; Pinacoloxymethylphosphoryl fluoride; Pinacolyl methylfluorophosphonate; Pinacolyl methylphosphonofluoridate; PMFP; Zoman; 1,2,2-Trimethylpropyl methylphosphonofluoridate; 3,3-Dimethyl-n-but-2-yl methylphosphonofluoridate; Methylphosphonofluoridic acid 1,2,2-trimethylpropyl ester; Soman # 1; Soman # 2; Pinacolyl methylphosphonofluoridate, diastereomer # 1; Pinacolyl methylphosphonofluoridate, diastereomer # 2; pinacolyl methylphosphonofluoridate, diastereomer 2
• Information on this page:
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
• Options:
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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Normal alkane RI, non-polar column, temperature ramp

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Normal alkane RI, non-polar column, custom temperature program

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Normal alkane RI, polar column, custom temperature program

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kostiainen, 2000
Kostiainen, O., Gas Chromatography in Screening of Chemicals Related to the Chemical Weapons Convention in Encyclopedia of Analytical Chemistry, Meyers, R.A., ed(s)., John Wiley Sons Ltd, Chichester, 2000, 963-979. [all data]

Kaipainen, Kostiainen, et al., 1992
Kaipainen, A.; Kostiainen, O.; Riekkola, M.-L., Identification of chemical warfare agents in air samples using capillary column gas chromatography with three simultaneous detectors, J. Microcolumn Sep., 1992, 4, 3, 245-251, https://doi.org/10.1002/mcs.1220040311 . [all data]

Hancock and Peters, 1991
Hancock, J.R.; Peters, G.R., Retention index monitoring of compounds of chemical defence interest using thermal desorption gas chromatography, J. Chromatogr., 1991, 538, 2, 249-257, https://doi.org/10.1016/S0021-9673(01)88845-2 . [all data]

D'Agostino and Provost, 1985
D'Agostino, P.A.; Provost, L.R., Gas chromatographic retention indices of chemical warfare agents and simulants, J. Chromatogr., 1985, 331, 47-54, https://doi.org/10.1016/0021-9673(85)80005-4 . [all data]

Söderström, Ketola, et al., 1995
Söderström, M.T.; Ketola, R.A.; Kostiainen, O., Identification of some nerve agent homologues and dialkyl methylphosphonates by gas chromatography/Fourier transform infrared spectrometry. Part II. Spectral search with the help of retention indices, Fresenius J. Anal. Chem., 1995, 352, 6, 550-556, https://doi.org/10.1007/BF00323072 . [all data]

Staples, 2006
Staples, E.J., Creating a compound library for chemical warfare agents for the ZNose, 2006, retrieved from http://www.estcal.com/TechPapers/Security/CWA-Libraries.pdf. [all data]

Tsunoda, 2005
Tsunoda, N., The sarin incidents in Japan and mass spectrometry, J. MAss Spectrom. Soc. Japan, 2005, 53, 3, 157-163, https://doi.org/10.5702/massspec.53.157 . [all data]

Soderstrom, White, et al., 2001
Soderstrom, M.; White, E.; Abis, L.; Sliwakowski, M., Summary report of the eight meeting of the validation group for the updating of the central OPCW analytical database, 28-29 November 2000, CS-2001-2242, Verification Division S/239/2001, 2001, 14. [all data]

OPCW, 1997
OPCW, Conference of the States Parties C-I/DEC.64 (22 May 1997), 1997, retrieved from http://www.opcw.org/html/global/c_series/csp1/CI_DEC64.html. [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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