Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

3-Pentanone

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, M. Frenkel director
BS - R.L. Brown and S.E. Stein
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein
AC - W.E. Acree, Jr., J.S. Chickos
DH - E.S. Domalski and E.D. Hearing

Quantity Value Units Method Reference Comment
Tboil375. ± 1.KAVGN/AAverage of 53 out of 54 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus234.15KN/ACollerson, Counsell, et al., 1965Uncertainty assigned by TRC = 0.02 K; TRC
Tfus234.18KN/ACollerson, Counsell, et al., 1965Uncertainty assigned by TRC = 0.01 K; TRC
Tfus233.35KN/ATimmermans, 1952Uncertainty assigned by TRC = 0.4 K; TRC
Tfus231.2KN/ATimmermans, 1927Uncertainty assigned by TRC = 1.5 K; TRC
Tfus231.15KN/ATimmermans and Mattaar, 1921Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Ttriple234.16KN/AAndon, Counsell, et al., 1968Crystal phase 1 phase; Uncertainty assigned by TRC = 0.03 K; TRC
Quantity Value Units Method Reference Comment
Tc561.5KN/AMajer and Svoboda, 1985 
Tc561.46KN/AAmbrose, Broderick, et al., 1974Uncertainty assigned by TRC = 0.2 K; TRC
Tc560.9KN/AKobe, Crawford, et al., 1955Uncertainty assigned by TRC = 0.56 K; TRC
Quantity Value Units Method Reference Comment
Pc37.29barN/AAmbrose, Broderick, et al., 1974Uncertainty assigned by TRC = 0.10 bar; TRC
Pc37.40barN/AKobe, Crawford, et al., 1955Uncertainty assigned by TRC = 0.414 bar; TRC
Quantity Value Units Method Reference Comment
rhoc2.97mol/lN/AKobe, Crawford, et al., 1955Uncertainty assigned by TRC = 0.35 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap38.68kJ/molN/AMajer and Svoboda, 1985 
Deltavap38.52kJ/molVUchytilova, Majer, et al., 1983ALS
Deltavap38.5kJ/molCUchytilova, Majer, et al., 1983AC
Deltavap38.7 ± 0.3kJ/molGCCSaluja, Peacock, et al., 1979AC
Deltavap38.6kJ/molN/AAmbrose, Ellender, et al., 1975AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
33.45375.2N/AMajer and Svoboda, 1985 
35.9 ± 0.2332.N/ABaglay, Gurariy, et al., 1988Based on data from 290. - 375. K.; AC
36.6344.AStephenson and Malanowski, 1987Based on data from 329. - 426. K.; AC
33.7436.AStephenson and Malanowski, 1987Based on data from 421. - 502. K.; AC
33.3509.AStephenson and Malanowski, 1987Based on data from 494. - 561. K.; AC
36.6344.A,GS,EBStephenson and Malanowski, 1987Based on data from 329. - 384. K. See also Ambrose, Ellender, et al., 1975.; AC
36.1 ± 0.1335.CHales, Lees, et al., 1967AC
34.9 ± 0.1354.CHales, Lees, et al., 1967AC
33.5 ± 0.1375.CHales, Lees, et al., 1967AC
36.9303.N/ARintelen, Saylor, et al., 1937Based on data from 283. - 323. K.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A (kJ/mol) beta Tc (K) Reference Comment
298. - 375.56.130.2923561.5Majer and Svoboda, 1985 

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A B C Reference Comment
329.69 - 384.54.149171309.653-59.032Collerson, Counsell, et al., 1965, 2 
309.51 - 374.82.86542716.17-125.978Dreisbach and Shrader, 1949Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
11.59234.2Acree, 1991AC

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.1109118.5crystaline, IIIcrystaline, IIAndon, Counsell, et al., 1968, 2DH
0.0096180.crystaline, IIcrystaline, IAndon, Counsell, et al., 1968, 2DH
11.594234.16crystaline, IliquidAndon, Counsell, et al., 1968, 2DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
0.96118.5crystaline, IIIcrystaline, IIAndon, Counsell, et al., 1968, 2DH
0.04180.crystaline, IIcrystaline, IAndon, Counsell, et al., 1968, 2DH
49.51234.16crystaline, IliquidAndon, Counsell, et al., 1968, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Collerson, Counsell, et al., 1965
Collerson, R.R.; Counsell, J.F.; Handley, R.; Martin, J.F.; Sprake, C.H.S., 677. Thermodynamic properties of organic oxygen compounds. Part XV. Purification and vapour pressures of some ketones and ethers, J. Chem. Soc., 1965, 3697, https://doi.org/10.1039/jr9650003697 . [all data]

Timmermans, 1952
Timmermans, J., Freezing points of organic compounds. VVI New determinations., Bull. Soc. Chim. Belg., 1952, 61, 393. [all data]

Timmermans, 1927
Timmermans, J., The Melting Point of Organic Substances, Bull. Soc. Chim. Belg., 1927, 36, 502. [all data]

Timmermans and Mattaar, 1921
Timmermans, J.; Mattaar, J.F., Freezing points of orgainic substances VI. New experimental determinations., Bull. Soc. Chim. Belg., 1921, 30, 213. [all data]

Andon, Counsell, et al., 1968
Andon, R.J.L.; Counsell, J.F.; Martin, J.F., Thermodynamic properties of organic oxygen compounds. Part XX. The low- temperature heat capacity and entropy of C4 and C5 ketones., J. Chem. Soc. A, 1968, 1968, 1894-7. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Ambrose, Broderick, et al., 1974
Ambrose, D.; Broderick, B.E.; Townsend, R., The Critical Temperatures and Pressures of Thirty Organic Compounds, J. Appl. Chem. Biotechnol., 1974, 24, 359. [all data]

Kobe, Crawford, et al., 1955
Kobe, K.A.; Crawford, H.R.; Stephenson, R.W., Critical Properties and Vapor Pressures of Some Ketones, Ind. Eng. Chem., 1955, 47, 1767-72. [all data]

Uchytilova, Majer, et al., 1983
Uchytilova, V.; Majer, V.; Svoboda, V.; Hynek, V., Enthalpies of vaporization and cohesive enrgies for seven aliphatic ketones, J. Chem. Thermodyn., 1983, 15, 853-858. [all data]

Saluja, Peacock, et al., 1979
Saluja, P.P.S.; Peacock, L.A.; Fuchs, R., Enthalpies of interaction of aliphatic ketones with polar and nonpolar solvents, J. Am. Chem. Soc., 1979, 101, 1958-1962. [all data]

Ambrose, Ellender, et al., 1975
Ambrose, D.; Ellender, J.H.; Lees, E.B.; Sprake, C.H.S.; Townsend, R., Thermodynamic properties of organic oxygen compounds XXXVIII. Vapour pressures of some aliphatic ketones, The Journal of Chemical Thermodynamics, 1975, 7, 5, 453-472, https://doi.org/10.1016/0021-9614(75)90275-X . [all data]

Baglay, Gurariy, et al., 1988
Baglay, A.K.; Gurariy, L.L.; Kuleshov, G.G., Physical properties of compounds used in vitamin synthesis, J. Chem. Eng. Data, 1988, 33, 512-518. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Hales, Lees, et al., 1967
Hales, J.L.; Lees, E.B.; Ruxton, D.J., Thermodynamic properties of organic oxygen compounds. Part 18.-Vapour heat capacities and heats of vaporization of ethyl ketone, ethyl propyl ketone, methyl isopropyl ketone, and methyl phenyl ether, Trans. Faraday Soc., 1967, 63, 1876. [all data]

Rintelen, Saylor, et al., 1937
Rintelen, J.C.; Saylor, J.H.; Gross, P.M., The Densities and Vapor Pressures of Some Alkylbenzenes, Aliphatic Ketones and n-Amyl Chloride 1, J. Am. Chem. Soc., 1937, 59, 6, 1129-1130, https://doi.org/10.1021/ja01285a050 . [all data]

Collerson, Counsell, et al., 1965, 2
Collerson, R.R.; Counsell, J.F.; Handley, R.; Martin, J.F.; Sprake, C.H.S., Thermodynamic Properties of Organic Oxygen Compounds. Part XV. Purification and Vapour Pressures of Some Ketones and Ethers, J. Chem. Soc., 1965, 3697-3700, https://doi.org/10.1039/jr9650003697 . [all data]

Dreisbach and Shrader, 1949
Dreisbach, R.R.; Shrader, S.A., Vapor Pressure--Temperature Data on Some Organic Compounds, Ind. Eng. Chem., 1949, 41, 12, 2879-2880, https://doi.org/10.1021/ie50480a054 . [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]

Andon, Counsell, et al., 1968, 2
Andon, R.J.L.; Counsell, J.F.; Martin, J.F., Thermodynamic properties of organic oxygen compounds. Part XX. The low-temperature heat capacity and entropy of C4 and C5 ketones, J. Chem. Soc. A, 1968, 1894-1897. [all data]


Notes

Go To: Top, Phase change data, References