Aluminum, chlorodiethyl-


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-91.35 ± 0.84kcal/molReviewMartinho SimõesSelected data. The enthalpy of formation relies on -44.8 ± 1.2 kcal/mol for the enthalpy of formation of Al(Et)3(l).
Δfliquid-101.1 ± 0.86kcal/molReviewMartinho Simões 
Δfliquid-56.84 ± 0.72kcal/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Δcliquid-866.99 ± 0.69kcal/molCC-SBPawlenko, 1969The enthalpy of combustion was corrected according to the method used in Pawlenko, 1969.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

2Hydrogen chloride (g) + Aluminum, chlorodiethyl- (l) = AlCl3 (cr) + 2Ethane (g)

By formula: 2HCl (g) + C4H10AlCl (l) = AlCl3 (cr) + 2C2H6 (g)

Quantity Value Units Method Reference Comment
Δr-63.34 ± 0.79kcal/molRSCShaulov and Shmyreva, 1968The reaction enthalpy was derived from data in Shaulov and Shmyreva, 1968.

AlCl3 (cr) + 2Aluminum, triethyl- (l) = 3Aluminum, chlorodiethyl- (l)

By formula: AlCl3 (cr) + 2C6H15Al (l) = 3C4H10AlCl (l)

Quantity Value Units Method Reference Comment
Δr-16.0 ± 0.31kcal/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

Aluminum, dichloroethyl- (l) + Aluminum, chlorodiethyl- (l) = C6H15Al2Cl3 (l)

By formula: C2H5AlCl2 (l) + C4H10AlCl (l) = C6H15Al2Cl3 (l)

Quantity Value Units Method Reference Comment
Δr-0.55 ± 0.05kcal/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

Aluminum, dichloroethyl- (l) + Aluminum, triethyl- (l) = 2Aluminum, chlorodiethyl- (l)

By formula: C2H5AlCl2 (l) + C6H15Al (l) = 2C4H10AlCl (l)

Quantity Value Units Method Reference Comment
Δr-9.4 ± 0.2kcal/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Pawlenko, 1969
Pawlenko, S., Chem. Ber., 1969, 102, 1937. [all data]

Shaulov and Shmyreva, 1968
Shaulov, Yu.Kh.; Shmyreva, G.O., Russ. J. Phys. Chem., 1968, 42, 1008. [all data]

Smith, 1974
Smith, M.B., J. Organometal. Chem., 1974, 76, 171. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]


Notes

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