2-Biphenylcarboxylic acid

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δcsolid-1480.8 ± 1.5kcal/molCcbBrull, 1935Reanalyzed by Cox and Pilcher, 1970, Original value = -1481.62 kcal/mol; Corresponding Δfsolid = -83.44 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil616.7KN/AWeast and Grasselli, 1989BS
Tboil616. to 617.KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Tfus387.KN/ABuckingham and Donaghy, 1982BS
Tfus382.KN/ACastro, Andrews, et al., 1958Uncertainty assigned by TRC = 3. K; TRC
Tfus384.KN/ADannley and Zaremsky, 1955Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Δsub29.0 ± 1.0kcal/molCMatos, Miranda, et al., 2004AC

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
472.20.013Weast and Grasselli, 1989BS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brull, 1935
Brull, L., Sui calori di combustione di alcuni derivati del bifenil, Gazz. Chim. Ital., 1935, 65, 19-28. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Castro, Andrews, et al., 1958
Castro, C.E.; Andrews, L.J.; Keefer, R.M., Molecular Complexes of Hindered Biphenyl Derivatives, J. Am. Chem. Soc., 1958, 80, 2322-6. [all data]

Dannley and Zaremsky, 1955
Dannley, R.L.; Zaremsky, B., Free Radical Aromatic Substitution V. The Reaction of Benzoyl Peroxide with Alkylbenzenes, J. Am. Chem. Soc., 1955, 77, 1588. [all data]

Matos, Miranda, et al., 2004
Matos, M. Agostinha R.; Miranda, Margarida S.; Martins, Diana V.S.S.; Pinto, Nat«65533»lia A.B.; Morais, Victor M.F.; Liebman, Joel F., Thermochemistry of biphenylcarboxylic and dicarboxylic acids. A combined experimental and theoretical studyThis paper is dedicated to Kurt Mislow, a pioneering biphenyl stereochemist, on the occasion of his 80th birthday., Org. Biomol. Chem., 2004, 2, 9, 1353, https://doi.org/10.1039/b401605j . [all data]


Notes

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