Phenothiazine
- Formula: C12H9NS
- Molecular weight: 199.272
- IUPAC Standard InChIKey: WJFKNYWRSNBZNX-UHFFFAOYSA-N
- CAS Registry Number: 92-84-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 10H-Phenothiazine; Contaverm; Danikoropa; Dibenzothiazine; Dibenzo-1,4-thiazine; Early bird wormer; ENT 38; Feeno; Fenoverm; Nemazene; Nexarbol; Orimon; Padophene; Penthazine; Phenegic; Phenoverm; Phenovis; Phenoxur; Phenthiazine; Phenzeen; Reconox; Thiodiphenylamine; AFI-Tiazin; Agrazine; Antiverm; Dibenzo-p-thiazine; Fenothiazine; Fenotiazina; Fentiazin; Helmetina; Lethelmin; Nemazine; Phenosan; Souframine; Thiodifenylamine; Thiodiphenylamin; Tiodifenilamina; Vermitin; Wurm-Thional; XL-50; Biverm; Dibenzoparathiazine; 10H-Phenothiazin; EPA Pesticide Chemical Code 064501; Promethazine M (ring); Alimemazine M (ring); Dixyrazine M (ring); Perazine M (ring); Pecazine M (ring); Mequitazine M (ring)
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 644.2 | K | N/A | Aldrich Chemical Company Inc., 1990 | BS |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 458.39 | K | N/A | Donnelly, Drewes, et al., 1990 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tfus | 457.5 | K | N/A | Plato and Glasgow, 1969 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tfus | 458.5 | K | N/A | Plato and Glasgow, 1969 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tfus | 457.55 | K | N/A | Cullinane and Rees, 1940 | Uncertainty assigned by TRC = 0.4 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 111.45 ± 0.37 | kJ/mol | C | Sabbah and El Watik, 1992 | ALS |
ΔsubH° | 114.5 ± 0.4 | kJ/mol | C | Sabbah and El Watik, 1992 | AC |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
86.0 | 351. | A | Stephenson and Malanowski, 1987 | Based on data from 336. to 395. K. See also Nelson and Smith, 1942.; AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
25.660 | 458.40 | N/A | Sabbah and El Watik, 1992 | DH |
28.4 | 457.2 | DSC | Gupta, Singh, et al., 2007 | AC |
25.7 | 458.4 | N/A | Sabbah and El Watik, 1992 | AC |
26.92 | 458.2 | N/A | Acree, 1991 | AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc.,
Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]
Donnelly, Drewes, et al., 1990
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W.,
Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry,
Thermochim. Acta, 1990, 167, 2, 155, https://doi.org/10.1016/0040-6031(90)80476-F
. [all data]
Plato and Glasgow, 1969
Plato, C.; Glasgow, A.R., Jr.,
Differential scanning calorimetry as a general method for determining the purity and heat of fusion of high-purity organic chemicals. Application to 95 compounds,
Anal. Chem., 1969, 41, 2, 330, https://doi.org/10.1021/ac60271a041
. [all data]
Cullinane and Rees, 1940
Cullinane, N.M.; Rees, W.T.,
Isomorphous relationships of some organic compounds of analogous constitution,
Trans. Faraday Soc., 1940, 36, 507. [all data]
Sabbah and El Watik, 1992
Sabbah, R.; El Watik, L.,
Etude thermodynamique de la phenoxazine et de la phenotiazine,
Thermochim. Acta, 1992, 197, 381-390. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Nelson and Smith, 1942
Nelson, O.A.; Smith, L.E.,
The Vapor Pressure of Phenothiazine 1,
J. Am. Chem. Soc., 1942, 64, 12, 3035-3037, https://doi.org/10.1021/ja01264a086
. [all data]
Gupta, Singh, et al., 2007
Gupta, R.K.; Singh, S.K.; Singh, R.A.,
Some physicochemical studies on organic eutectics,
Journal of Crystal Growth, 2007, 300, 2, 415-420, https://doi.org/10.1016/j.jcrysgro.2006.12.017
. [all data]
Acree, 1991
Acree, William E.,
Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation,
Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point ΔfusH Enthalpy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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