bis(trifluoromethyl) peroxide
- Formula: C2F6O2
- Molecular weight: 170.0106
- IUPAC Standard InChIKey: BPXRXDJNYFWRDI-UHFFFAOYSA-N
- CAS Registry Number: 927-84-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Di(trifluoromethyl)peroxide
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -360.2 ± 3.0 | kcal/mol | Eqk | Levy and Kennedy, 1972 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
=
+ CF4O
By formula: C2F6O2 = CF2O + CF4O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 24.50 ± 0.70 | kcal/mol | Eqk | Levy and Kennedy, 1972 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Levy and Kennedy, 1972
Levy, J.B.; Kennedy, R.C.,
Bistrifluoromethyl peroxide. I. Thermodynamics of the equilibrium with carbonyl fluoride and trifluoromethyl hypofluorite,
J. Am. Chem. Soc., 1972, 94, 3302-3305. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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