2,3-Dehydro-1,8-cineole
- Formula: C10H16O
- Molecular weight: 152.2334
- IUPAC Standard InChIKey: LOOYOTLEOHYYOV-UHFFFAOYSA-N
- CAS Registry Number: 92760-25-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Dehydrocineole; 1,3,3-Trimethyl-2-oxabicyclo[2.2.2]oct-5-ene; Dehydro-1,8-cineole; Dehydro-1,8-cineol; 1,8-Dehydrocineole; 2,3-dehydro-1,8-cineol; Dehydro-1,8-cyneole; Dehydro-1.8-cineole; 1,8-Cineole, 2,3-dehydro-; 1,8-Cineole, dehydro-
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- Other data available:
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Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5 MS | HP-5 MS | DBP-5 | DBP-5 | DB-5 |
Column length (m) | 30. | 30. | 25. | 25. | 30. |
Carrier gas | Helium | Helium | Helium | Helium | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.22 | 0.22 | 0.25 |
Tstart (C) | 100. | 50. | 40. | 40. | 60. |
Tend (C) | 220. | 280. | 250. | 250. | 220. |
Heat rate (K/min) | 2. | 4. | 3. | 3. | 4. |
Initial hold (min) | 1. | 1. | 5. | ||
Final hold (min) | 10. | 10. | |||
I | 991. | 989. | 963. | 963. | 993. |
Reference | Pripdeevech, Chumpolsri, et al., 2010 | Zhao, Zeng, et al., 2009 | Heravi and Sereshti, 2007 | Sereshti and Samadi, 2007 | Morteza-Semnani K., Akbarzadeh M., et al., 2006 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | DB-5 | SPB-5 | DB-5 | DB-5 |
Column length (m) | 30. | 30. | 30. | 30. | 30. |
Carrier gas | Hydrogen | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.249 | 0.53 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 70. | 60. | 100. | 60. | 60. |
Tend (C) | 280. | 290. | 250. | 220. | 220. |
Heat rate (K/min) | 4. | 3. | 5. | 4. | 4. |
Initial hold (min) | 4. | 5. | 4. | ||
Final hold (min) | |||||
I | 991. | 986. | 1006. | 991. | 993. |
Reference | Pino, Marbot, et al., 2006 | Bos, Stojanova, et al., 2005 | Kilic, Kollmannsberger, et al., 2005 | Morteza-Semnani, Akbarzadeh, et al., 2005 | Morteza-Semnani and Saeedi, 2005 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | BP-1 | SE-54 | DB-5 | HP-5 | DB-1 |
Column length (m) | 50. | 30. | 30. | 25. | 60. |
Carrier gas | He | He | N2 | N2 | |
Substrate | |||||
Column diameter (mm) | 0.22 | 0.25 | 0.25 | 0.2 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.5 | 0.25 |
Tstart (C) | 60. | 60. | 35. | 30. | 80. |
Tend (C) | 220. | 260. | 220. | 280. | 210. |
Heat rate (K/min) | 2. | 2. | 2.5 | 3. | 3. |
Initial hold (min) | 5. | ||||
Final hold (min) | 20. | 6. | 15. | ||
I | 978. | 989. | 991. | 993. | 985. |
Reference | Blanc, Muselli, et al., 2004 | Kilic, Hafizoglu, et al., 2004 | Rohloff, Mordal, et al., 2004 | Shafi, Nambiar, et al., 2004 | Ueno, Masuda, et al., 2004 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5MS | DB-5 | DB-1 | DB-5 | DB-5 |
Column length (m) | 30. | 50. | 50. | 30. | 30. |
Carrier gas | He | He | N2 | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.2 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 50. | 95. | 60. | 60. |
Tend (C) | 275. | 220. | 240. | 280. | 240. |
Heat rate (K/min) | 4. | 3. | 4. | 3. | 3. |
Initial hold (min) | 2. | ||||
Final hold (min) | 30. | ||||
I | 991. | 990. | 989. | 983. | 993. |
Reference | Afsharypuor and Jahromy, 2003 | Masotti, Juteau, et al., 2003 | Perez-Alonso, Velasco-Negueruela, et al., 2003 | Caredda, Marongiu, et al., 2002 | Flamini, Ertugrul, et al., 2002 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5 | CP Sil 5 CB | DB-1 | DB-1 | HP-5 |
Column length (m) | 30. | 25. | 30. | 50. | 30. |
Carrier gas | He | He | N2 | N2 | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | ||
Tstart (C) | 50. | 60. | 60. | 80. | 60. |
Tend (C) | 200. | 220. | 250. | 225. | 220. |
Heat rate (K/min) | 3. | 5. | 4. | 4. | 5. |
Initial hold (min) | 10. | 10. | |||
Final hold (min) | |||||
I | 988. | 981. | 989. | 972. | 993. |
Reference | Isidorov and Jdanova, 2002 | Monfared, Davarani, et al., 2002 | Norouzi-Arasi, Yavari, et al., 2002 | Palá-Paúl, Pérez-Alonso, et al., 2002 | Campeol, Flamini, et al., 2001 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | RTX-1 | CP Sil 5 CB | DB-5 | HP-5 | SE-30 |
Column length (m) | 30. | 25. | 30. | 100. | |
Carrier gas | N2 | N2 | He | N2 | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Phase thickness (μm) | 0.25 | 0.39 | 0.25 | ||
Tstart (C) | 60. | 60. | 60. | 35. | 45. |
Tend (C) | 300. | 220. | 240. | 200. | 250. |
Heat rate (K/min) | 4. | 5. | 3. | 6. | 4. |
Initial hold (min) | 2. | 1. | |||
Final hold (min) | |||||
I | 982. | 986. | 992. | 1004. | 985. |
Reference | Kalemba, 1999 | Rustaiyan and Nadji, 1999 | Tellez, Canel, et al., 1999 | Larsen and Frisvad, 1995 | Peacock and Kuneman, 1985 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pripdeevech, Chumpolsri, et al., 2010
Pripdeevech, P.; Chumpolsri, W.; Suttiarporn, P.; Wongpornchai, S.,
The chemical composition and antioxidant activities of Basil from Thailand using retention indices and comprehensive two-dimensional gas chromatography,
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Zhao, Zeng, et al., 2009
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Comparative analysis of essential oils from eight herbal medicines with pungent flavor and cool nature by GC-MS and chemometric resolution methods,
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Heravi and Sereshti, 2007
Heravi, M.J.; Sereshti, H.,
Determination of Essential Oil Components of Artemisia haussknechtii Boiss. using Simultaneous Hydrodistillation-Static Headspace Liquid Phase Microextraction - Gas Chromatography Mass Spectrometry,
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Sereshti and Samadi, 2007
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Comparison of hydrodistillation-headspace liquid phase microextraction techniques with hydrodistillation in determination of essential oils in Artemisia Haussknechtii Boiss,
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Morteza-Semnani K., Akbarzadeh M., et al., 2006
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The essential oil composition of Eupatorium cannabinum L. from Iran,
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Pino, Marbot, et al., 2006
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Aromatic Plants from Western Cuba VII. Composition of the Leaf Oil of Psidium wrightii KRug et Urb., Lantana involucrata L., Cinnamonum montanum (Sw.) Berchtold et J. Persl. and Caesalpinia violacea (Mill.) Standley,
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Bos, Stojanova, et al., 2005
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Volatile components of the aerial parts of Artemisia pontica L. grown in Bulgaria,
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Kilic, Kollmannsberger, et al., 2005
Kilic, A.; Kollmannsberger, H.; Nitz, S.,
Glycosidically bound volatiles and flavor precursors in Laurus nobilis L.,
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Morteza-Semnani, Akbarzadeh, et al., 2005
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Essential oil composition of Artemisia fragrans Willd. from Iran,
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Morteza-Semnani and Saeedi, 2005
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The essential oil composition of Phlomis bruguieri Desf. from Iran,
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Blanc, Muselli, et al., 2004
Blanc, M.-C.; Muselli, A.; Bradesi, P.; Casanova, J.,
Chemical composition and variability of the essential oil of Inula graveolens from Corsica,
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Kilic, Hafizoglu, et al., 2004
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Volatile constituents and key odorants in leaves, buds, flowers, and fruits of Laurus nobilis L.,
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Rohloff, Mordal, et al., 2004
Rohloff, J.; Mordal, R.; Dragland, S.,
Chemotypical variation of tansy (Tanacetum vulgare L.) from 40 different locations in Norway,
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Shafi, Nambiar, et al., 2004
Shafi, P.M.; Nambiar, M.K.G.; Clery, R.A.; Sarma, Y.R.; Veena, S.S.,
Composition and antifungal activity of the oil of Artemisia nilagirica (Clarke) Pamp,
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Ueno, Masuda, et al., 2004
Ueno, T.; Masuda, H.; Ho, C.-T.,
Formation mechanism of p-methylacetophenone from citral via a tert-alkoxy radical intermediate,
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Afsharypuor and Jahromy, 2003
Afsharypuor, S.; Jahromy, M.M.,
Constituents of the essential oil from Tanacetum lingulatum (Boiss.) Bornm.,
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Masotti, Juteau, et al., 2003
Masotti, V.; Juteau, F.; Bessière, J.M.; Viano, J.,
Seasonal and phenological variations of the essential oil from the narrow endemic species Artemisia molinieri and its biological activities,
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Perez-Alonso, Velasco-Negueruela, et al., 2003
Perez-Alonso, M.J.; Velasco-Negueruela, A.; Palá-Paúl, J.; Sanz, J.,
Variations in the essential oil composition of Artemisia pedemontana gathered in Spain: chemotype camphor-1,8-cineole and chemotype davanone,
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Caredda, Marongiu, et al., 2002
Caredda, A.; Marongiu, B.; Porcedda, S.; Soro, C.,
Supercritical carbon dioxide extraction and characterization of Laurus nobilis essential oil,
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Flamini, Ertugrul, et al., 2002
Flamini, G.; Ertugrul, K.; Cioni, P.L.; Morelli, I.; Dural, H.; Bagci, Y.,
Volatile constituents of two endemic Centaurea species from Turkey: C. pseudoscabiosa subsp. pseudoscabiosa and C. hadimensis,
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Isidorov and Jdanova, 2002
Isidorov, V.; Jdanova, M.,
Volatile organic compounds from leaves litter,
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Monfared, Davarani, et al., 2002
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Composition of the essential oil of Tanacetum balsamita L. ssp. balsamitoides (Schultz Bip.) Grierson from Iran,
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Norouzi-Arasi, Yavari, et al., 2002
Norouzi-Arasi, H.; Yavari, I.; Ghaffarzadeh, F.; Mortazavi, M.-S.,
Volatile constituents of Cymbopogon olivieri (Boiss.) Bor from Iran,
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Palá-Paúl, Pérez-Alonso, et al., 2002
Palá-Paúl, J.; Pérez-Alonso, M.J.; Velasco-Negueruela, A.; Sanz, J.,
Analysis by gas chromatography-mass spectrometry of the volatile components of Ageratina adenophora Spreng., growing in the Canary Islands,
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Campeol, Flamini, et al., 2001
Campeol, E.; Flamini, G.; Chericoni, S.; Catalano, S.; Cremonini, R.,
Volatile compounds from three cultivars of Olea europaea from Italy,
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Kalemba, 1999
Kalemba, D.,
Constituents of the essential oil of Artemisia asiatica Nakai,
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Rustaiyan and Nadji, 1999
Rustaiyan, A.; Nadji, K.,
Composition of the essential oils of Nepeta ispahanica Boiss. and Nepeta binaludensis Jamzad from Iran,
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Tellez, Canel, et al., 1999
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Differential accumulation of isoprenoids in glanded and glandless Artemisia annua L,
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Larsen and Frisvad, 1995
Larsen, T.O.; Frisvad, J.C.,
Comparison of different methods for collection of volatile chemical markers from fungi,
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Peacock and Kuneman, 1985
Peacock, V.E.; Kuneman, D.W.,
Inhibition of the formation of α-p-dimethylstyrene and p-cymen-8-ol in a carbonated citral-containing beverage system,
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Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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