Biphenyl

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Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

ΔcH°solid (kJ/mol) Method Reference Comment
-6248. ± 2.CcbMontgomery, Rossini, et al., 1978Corresponding ΔfHºsolid = 96.73 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-6251.8 ± 1.4CcbColeman and Pilcher, 1966Corresponding ΔfHºsolid = 100.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-6248.2 ± 4.0CcbMackle and O'Hare, 1963Corresponding ΔfHºsolid = 96.90 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-6248.5 ± 1.6CcbParks and Vaughan, 1951Reanalyzed by Cox and Pilcher, 1970, Original value = -6247.97 kJ/mol; Corresponding ΔfHºsolid = 97.24 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-6248.8 ± 6.3CcbBrull, 1935Reanalyzed by Cox and Pilcher, 1970, Original value = -6247.80 kJ/mol; Corresponding ΔfHºsolid = 97.53 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-6243.CcbWieland, Heymann, et al., 1934Corresponding ΔfHºsolid = 92. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-6276.0CcbBarker, 1925Author was aware that data differs from previously reported values; Corresponding ΔfHºsolid = 125. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

References

Go To: Top, Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Montgomery, Rossini, et al., 1978
Montgomery, R.L.; Rossini, F.D.; Mansson, M., Enthalpies of combustion, vaporization, and formation of phenylbenzene, cyclohexylbenzene, and cyclohexylcyclohexane; enthalpy of hydrogenation of certain aromatic systems, J. Chem. Eng. Data, 1978, 23, 125-129. [all data]

Coleman and Pilcher, 1966
Coleman, D.J.; Pilcher, G., Heats of combustion of biphenyl, bibenzyl, naphthalene, anthracene, and phenanthrene, Trans. Faraday Soc., 1966, 62, 821-827. [all data]

Mackle and O'Hare, 1963
Mackle, H.; O'Hare, P.A.G., A high-precision aneroid semi-micro combustion calorimeter, Trans. Faraday Soc., 1963, 59, 2693-2701. [all data]

Parks and Vaughan, 1951
Parks, G.S.; Vaughan, L.M., The heat of combustion of biphenyl, J. Am. Chem. Soc., 1951, 73, 2380-2381. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Brull, 1935
Brull, L., Sui calori di combustione di alcuni derivati del bifenil, Gazz. Chim. Ital., 1935, 65, 19-28. [all data]

Wieland, Heymann, et al., 1934
Wieland, H.; Heymann, K.; Tsatsas, T.; Juchum, D.; Varvoglis, G.; Labriola, G.; Dobbelstein, O.; Boyd-Barrett, H.S., Uber das Auftreten freier Radikale bei chemischen Reaktionen. VIII, Ann., 1934, 514, 145-181. [all data]

Barker, 1925
Barker, M.F., Calorific value and constitution, J. Phys. Chem., 1925, 29, 1345-1363. [all data]

Notes

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