C10H14


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C10H13- + Hydrogen cation = C10H14

By formula: C10H13- + H+ = C10H14

Quantity Value Units Method Reference Comment
Δr1546. ± 10.kJ/molG+TSMishima, Kinoshita, et al., 2002gas phase; Reprotonation likely to be on C-1, giving 1-alkyl-cycloheptatriene - JEB
Quantity Value Units Method Reference Comment
Δr1513. ± 8.4kJ/molIMREMishima, Kinoshita, et al., 2002gas phase; Reprotonation likely to be on C-1, giving 1-alkyl-cycloheptatriene - JEB

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C10H13- + Hydrogen cation = C10H14

By formula: C10H13- + H+ = C10H14

Quantity Value Units Method Reference Comment
Δr1546. ± 10.kJ/molG+TSMishima, Kinoshita, et al., 2002gas phase; Reprotonation likely to be on C-1, giving 1-alkyl-cycloheptatriene - JEB
Quantity Value Units Method Reference Comment
Δr1513. ± 8.4kJ/molIMREMishima, Kinoshita, et al., 2002gas phase; Reprotonation likely to be on C-1, giving 1-alkyl-cycloheptatriene - JEB

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mishima, Kinoshita, et al., 2002
Mishima, M.; Kinoshita, T.; Hattori, Y.; Takeuchi, K., Gas-phase acidities of cycloheptatrienes: effects of alkyl groups on the stability of carbanions, Eur. J. Mass Spectrom., 2002, 8, 1, 359-366, https://doi.org/10.1255/ejms.499 . [all data]


Notes

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