Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

1-Propene, homopolymer


Condensed phase thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
solid,1 bar78.99J/mol*KN/ADainton, Evans, et al., 1962glass phase; When extrapolated to 100% crystallinity, the entropy is 62.76 J/mol*K.

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
88.0298.1Passaglia and Kevorkian, 1963glass phase; T = 87 to 484 K. Unsmoothed experimental datum.
89.59298.15Dainton, Evans, et al., 1962glass phase; T = 20 to 310 K.
98.90298.15Wilkinson and Dole, 1962glass phase; T = 217 to 477 K. Cp = 0.510 + 0.00207t (-5 to 30°C) cal/g*K. Cp value calculated from equation.

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dainton, Evans, et al., 1962
Dainton, F.S.; Evans, D.M.; Hoare, F.E.; Melia, T.P., Thermodynamic functions of linear high polymers. Part IV. Stereospecific poly-a-olefines, Polymer, 1962, 3, 286-296. [all data]

Passaglia and Kevorkian, 1963
Passaglia, E.; Kevorkian, H.K., Specific heat of atactic and isotactic polypropylene and the entropy of the glass, J. Appl. Phys., 1963, 34(1), 90-97. [all data]

Wilkinson and Dole, 1962
Wilkinson, R.W.; Dole, M., Specific heat of synthetic high polymers. S. Isotactic and atactic polypropylene, J. Polymer Science, 1962, 58, 1089-1106. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, References