Phenol, 2,4,6-trichloro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil519.2KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Δvap67.2 ± 0.3kJ/molGSVerevkin, Emel'yanenko, et al., 2007Based on data from 343. to 375. K.; AC
Δvap66.1 ± 0.4kJ/molN/AMokbel, Pauchon, et al., 1995Based on data from 344. to 463. K. See also Verevkin, Emel'yanenko, et al., 2007.; AC
Quantity Value Units Method Reference Comment
Δsub82.3 ± 0.3kJ/molGSFreitas, Oliveira, et al., 2007Based on data from 299. to 340. K.; AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
62.5359.GSVerevkin, Emel'yanenko, et al., 2007Based on data from 343. to 375. K.; AC
58.2404.N/AMokbel, Pauchon, et al., 1995Based on data from 344. to 463. K. See also Verevkin, Emel'yanenko, et al., 2007.; AC
58.8364.AStephenson and Malanowski, 1987Based on data from 349. to 519. K. See also Stull, 1947.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
349.7 to 519.5.361862599.065-34.151Stull, 1947Coefficents calculated by NIST from author's data.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Verevkin, Emel'yanenko, et al., 2007
Verevkin, Sergey P.; Emel'yanenko, Vladimir N.; Klamt, Andreas, Thermochemistry of Chlorobenzenes and Chlorophenols: Ambient Temperature Vapor Pressures and Enthalpies of Phase Transitions, J. Chem. Eng. Data, 2007, 52, 2, 499-510, https://doi.org/10.1021/je060429r . [all data]

Mokbel, Pauchon, et al., 1995
Mokbel, I.; Pauchon, V.; Jose, J., Vapor pressures and sublimation pressures of 2,4-dichlorophenol, 2,6-dichlorophenol, and 2,4,6-trichlorophenol, ELDATA: Int. Electron. J. Phys. Chem. Data, 1995, 1, 1, 53. [all data]

Freitas, Oliveira, et al., 2007
Freitas, Vera L.S.; Oliveira, Liliana I.P.; Ribeiro da Silva, Maria D.M.C., Standard molar enthalpies of formation of the acetylpyridine isomers, The Journal of Chemical Thermodynamics, 2007, 39, 1, 39-43, https://doi.org/10.1016/j.jct.2006.06.004 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]


Notes

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