Dimethyl phosphite
- Formula: C2H7O3P
- Molecular weight: 110.0489
- IUPAC Standard InChIKey: HZCDANOFLILNSA-UHFFFAOYSA-N
- CAS Registry Number: 868-85-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Isotopologues:
- Other names: Phosphonic acid, dimethyl ester; Dimethoxyphosphine oxide; Dimethyl acid phosphite; Dimethyl hydrogen phosphite; Dimethyl phosphonate; Hydrogen dimethyl phosphite; Methyl phosphonate ((MeO)2HPO); O,O-Dimethyl phosphonate; (CH3O)2PHO; Phosphorous acid dimethyl ester; Dimethylester kyseliny fosforite; Dimethylfosfit; Dimethylfosfonat; NCI-C54773; Dimethyl ester of phosphonic acid; Dimethyl hydrogen phosphonate
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C2H6O3P- + =
By formula: C2H6O3P- + H+ = C2H7O3P
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 356.5 ± 3.6 | kcal/mol | G+TS | McDonald, Chowdhury, et al., 1987 | gas phase; Acidity between MeNO2, EtSH. Acid taken as (MeO)2P(O)H. |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 349.3 ± 3.5 | kcal/mol | IMRB | McDonald, Chowdhury, et al., 1987 | gas phase; Acidity between MeNO2, EtSH. Acid taken as (MeO)2P(O)H. |
ΔrG° | 351.0 ± 4.0 | kcal/mol | IMRB | Anderson, DePuy, et al., 1984 | gas phase; Between MeSH, H2S |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
McDonald, Chowdhury, et al., 1987
McDonald, R.M.; Chowdhury, A.K.; Gung, W.Y.; DeWitt, K.D.,
Nucleophilic Reactivity in Anionic Ion-Molecule Reactions
in Nucleophilicity, Harris, J.M, McManus, S.P. Eds., Amer. Chem. Soc, 1987. [all data]
Anderson, DePuy, et al., 1984
Anderson, D.R.; DePuy, C.H.; Filley, J.; Bierbaum, V.M.,
Gas Phase Chemistry of Trimethyl Phosphite,
J. Am. Chem. Soc., 1984, 106, 22, 6513, https://doi.org/10.1021/ja00334a009
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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