Dimethyl phosphite
- Formula: C2H7O3P
- Molecular weight: 110.0489
- IUPAC Standard InChIKey: HZCDANOFLILNSA-UHFFFAOYSA-N
- CAS Registry Number: 868-85-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Isotopologues:
- Other names: Phosphonic acid, dimethyl ester; Dimethoxyphosphine oxide; Dimethyl acid phosphite; Dimethyl hydrogen phosphite; Dimethyl phosphonate; Hydrogen dimethyl phosphite; Methyl phosphonate ((MeO)2HPO); O,O-Dimethyl phosphonate; (CH3O)2PHO; Phosphorous acid dimethyl ester; Dimethylester kyseliny fosforite; Dimethylfosfit; Dimethylfosfonat; NCI-C54773; Dimethyl ester of phosphonic acid; Dimethyl hydrogen phosphonate
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔvapH° | 46.7 | kJ/mol | GS | Butrow, Buchanan, et al., 2009 | Based on data from 243. to 443. K. |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
46.7 | 368. | N/A | Fan and Wang, 2010 | Based on data from 353. to 443. K. |
48.3 | 243. | GS | Butrow, Buchanan, et al., 2009 | Based on data from 243. to 443. K. |
47.9 | 263. | GS | Butrow, Buchanan, et al., 2009 | Based on data from 243. to 443. K. |
46.4 | 313. | GS | Butrow, Buchanan, et al., 2009 | Based on data from 243. to 443. K. |
46.0 | 333. | GS | Butrow, Buchanan, et al., 2009 | Based on data from 243. to 443. K. |
45.4 | 373. | GS | Butrow, Buchanan, et al., 2009 | Based on data from 243. to 443. K. |
38.7 | 361. | A | Stephenson and Malanowski, 1987 | Based on data from 346. to 456. K. See also Dykyj, 1970. |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Butrow, Buchanan, et al., 2009
Butrow, Ann B.; Buchanan, James H.; Tevault, David E.,
Vapor Pressure of Organophosphorus Nerve Agent Simulant Compounds,
J. Chem. Eng. Data, 2009, 54, 6, 1876-1883, https://doi.org/10.1021/je8010024
. [all data]
Fan and Wang, 2010
Fan, Chuan-Lei; Wang, Li-Sheng,
Vapor Pressure of Dimethyl Phosphite and Dimethyl Methylphosphonate,
J. Chem. Eng. Data, 2010, 55, 1, 479-481, https://doi.org/10.1021/je900258f
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Dykyj, 1970
Dykyj, J.,
Petrochemica, 1970, 10, 2, 51. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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