N-Nitrosodiphenylamine
- Formula: C12H10N2O
- Molecular weight: 198.2206
- IUPAC Standard InChI: InChI=1S/C12H10N2O/c15-13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
- IUPAC Standard InChIKey: UBUCNCOMADRQHX-UHFFFAOYSA-N
- CAS Registry Number: 86-30-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Benzenamine, N-nitroso-N-phenyl-; Diphenylamine, N-nitroso-; Diphenylnitrosamine; N-Nitroso-N-phenylaniline; N,N-Diphenylnitrosamine; Nitrosodiphenylamine; Redax; Retarder J; Vulcatard A; Vulkalent A; Vultrol; Diphenylnitrosamin; N-Nitrosodifenylamin; NCI-C02880; Vulcatard; Curetard A; Delac J; Difenylnitrosamin; Diphenyl N-nitrosoamine; Naugard tjb; Ndpa; NdphA; TJB; Vulcalent A; N-Nitroso-N-diphenylamine; N,N-Diphenyl-N-nitrosoamine; NSC 585; Ortard; Sconoc
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
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By formula: C12H11N + HNO2 = H2O + C12H10N2O
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -15.02 | kcal/mol | Cm | Swientoslawski, 1910 | solid phase |
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | SE-52 | 210. | 1865. | Gough and Webb, 1974 | He; Column length: 1.5 m |
Lee's RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-5 | 274.9 | Donnelly, Abdel-Hamid, et al., 1993 | 30. m/0.32 mm/0.25 μm, He, 40. C @ 3. min, 8. K/min, 285. C @ 29.5 min |
References
Go To: Top, Reaction thermochemistry data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Swientoslawski, 1910
Swientoslawski, W.,
Thermochemische Untersuchungen der organischen Verbindungen. Dritte Mitteilung. Stickstoffhaltige Verbindungen.,
Z. Phys. Chem., 1910, 72, 49-83. [all data]
Gough and Webb, 1974
Gough, T.A.; Webb, K.S.,
The Trace Detection of Some Non-Volatile Nitrosamines by Combined Gas Chromatography and Mass Spectrometry,
J. Chromatogr., 1974, 95, 1, 59-63, https://doi.org/10.1016/S0021-9673(00)84095-9
. [all data]
Donnelly, Abdel-Hamid, et al., 1993
Donnelly, J.R.; Abdel-Hamid, M.S.; Jeter, J.L.; Gurka, D.F.,
Application of gas chromatographic retention properties to the identification of environmental contaminants,
J. Chromatogr., 1993, 642, 1-2, 409-415, https://doi.org/10.1016/0021-9673(93)80106-I
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas Chromatography, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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