Alpha,N,N-dimethylaminophenylacetonitrile

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas52.66 ± 0.19kcal/molCcbWelle, Verevkin, et al., 1997 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid37.65 ± 0.16kcal/molCcbWelle, Verevkin, et al., 1997 
Quantity Value Units Method Reference Comment
Δcliquid-1388.05 ± 0.13kcal/molCcbWelle, Verevkin, et al., 1997 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap15.01 ± 0.10kcal/molVWelle, Verevkin, et al., 1997ALS
Δvap15.0kcal/molN/AWelle, Verevkin, et al., 1997DRB

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
351. to 352.0.001Frinton Laboratories Inc., 1986BS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
15.0 ± 0.1298. to 338.GSWelle, Verevkin, et al., 1997AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Welle, Verevkin, et al., 1997
Welle, F.M.; Verevkin, S.P.; Beckhaus, H.-D.; Ruchardt, C., Stabilization of the cyano(dimethylamino)methyl radical - synergistic effect due to interaction between α-cyano groups on the radical stabilization energy, Liebigs Ann., 1997, 155-163. [all data]

Frinton Laboratories Inc., 1986
Frinton Laboratories Inc., Catalog Number 11, Frinton Laboratories Inc., Vineland, NJ, 1986, 99. [all data]


Notes

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