ethyllithium


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas15.2 ± 0.53kcal/molReviewMartinho Simões 
Δfgas13.9 ± 1.3kcal/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-12.7 ± 0.48kcal/molReviewMartinho Simões 
Δfsolid-14.0 ± 1.3kcal/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Δcsolid-416.3 ± 1.3kcal/molCC-SBLebedev, Miroshnichenko, et al., 1962Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub27.9 ± 0.2kcal/molRSCChaikin, 1962MS

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
27.87315.5AStephenson and Malanowski, 1987Based on data from 298. to 333. K. See also Chaikin, 1962.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Lebedev, Miroshnichenko, et al., 1962
Lebedev, Y.A.; Miroshnichenko, E.A.; Chaikin, A.M., Dokl. Akad. Nauk SSSR, 1962, 145, 1288. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Chaikin, 1962
Chaikin, A.M., Zh. Fiz. Khim., 1962, 36, 130. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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