Methacrylamide
- Formula: C4H7NO
- Molecular weight: 85.1045
- IUPAC Standard InChIKey: FQPSGWSUVKBHSU-UHFFFAOYSA-N
- CAS Registry Number: 79-39-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 2-Propenamide, 2-methyl-; α-Methyl acrylic amide; Methacryamide; Methacrylic acid amide; Methacrylic amide; Methylacrylic amide; 2-Methylacrylamide; 2-Methylpropenamide; USAF RH-1; Amid kyseliny methakrylove; Mhoromer BM801; NSC 23772
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Condensed phase thermochemistry data
Go To: Top, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -59.06 ± 0.12 | kcal/mol | Ccr | Steele, Chirico, et al., 1991 | ALS |
ΔfH°solid | -60.2 ± 0.1 | kcal/mol | Ccb | Lebedeva, Gutner, et al., 1976 | Hfusion =4.2±0.2 kcal/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -556.25 ± 0.11 | kcal/mol | Ccr | Steele, Chirico, et al., 1991 | ALS |
ΔcH°solid | -555.1 ± 0.1 | kcal/mol | Ccb | Lebedeva, Gutner, et al., 1976 | Hfusion =4.2±0.2 kcal/mol; ALS |
Constant pressure heat capacity of solid
Cp,solid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
34.37 | 298.15 | N/A | T = 290 to 385 K. C/R(c) = 6.82 + 0.0352T (290 to 385 K), R = 8.31451 J/mol*K.; DH |
IR Spectrum
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Coblentz Society, Inc.
Condensed Phase Spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.
Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Additional Data
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Owner | COBLENTZ SOCIETY Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | DOW CORNING CORP. |
Source reference | COBLENTZ NO. 4286 |
Date | 1965/10/08 |
Name(s) | 2-methylacrylamide METHACRYLAMIDE |
State | SOLID (SPLIT MULL, FLUOROLUBE FOR 3800-1300 AND NUJOL FOR 1300-250 CM -1) |
Instrument | PERKIN-ELMER 521 (GRATING) |
Instrument parameters | FILTERS AT 3150, 2500, 2000, 1150, 700, 410; GRATING CHANGES AT 2000, 630 CM-1 |
Resolution | 4 |
Sampling procedure | TRANSMISSION |
Data processing | DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS) |
References
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Steele, Chirico, et al., 1991
Steele, W.V.; Chirico, R.D.; Nguyen, A.; Hossenlopp, I.A.; Smith, N.K.,
DIPPR PROJECT 871: Determination of ideal-gas enthalpies of formation for key compounds: The 1989 project results,
J. Chem. Thermodyn., 1991, 101-134. [all data]
Lebedeva, Gutner, et al., 1976
Lebedeva, N.D.; Gutner, N.M.; Kiseleva, N.N.,
Correlation of the departures from additivity in the enthalpies of formation of ethylene and benzene derivatives with the σp constants,
J. Org. Chem. USSR (Engl. Transl.), 1976, 12, 1594-1597. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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