Ethene, chlorotrifluoro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-124.9 ± 1.1kcal/molCcrErastov and Kolesov, 1982see Erastov, Kolesov, et al., 1981 AND Papina, Erastov, et al., 1981; ALS
Quantity Value Units Method Reference Comment
Δcliquid-195.0 ± 0.67kcal/molCcrErastov and Kolesov, 1982see Erastov, Kolesov, et al., 1981 AND Papina, Erastov, et al., 1981; ALS
Quantity Value Units Method Reference Comment
liquid52.739cal/mol*KN/AOliver, Grisard, et al., 1951DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
29.259244.80Oliver, Grisard, et al., 1951T = 16 to 245 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil244.8KN/AAldrich Chemical Company Inc., 1990BS
Tboil246.KN/APCR Inc., 1990BS
Quantity Value Units Method Reference Comment
Tfus118.3KN/AGolovanova and Kolesov, 1984Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Ttriple115.00KN/AOliver, Grisard, et al., 1951, 2Uncertainty assigned by TRC = 0.05 K; from melting curve in a calorimeter, To = 273.16 K; TRC
Quantity Value Units Method Reference Comment
Tc379.5 ± 0.8KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Pc260. ± 200.atmAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ρc4.72mol/lN/AOliver, Grisard, et al., 1951, 2Uncertainty assigned by TRC = 0.26 mol/l; mean value for 5 samples; TRC
Quantity Value Units Method Reference Comment
Δvap4.11kcal/molVErastov and Kolesov, 1982see Erastov, Kolesov, et al., 1981 AND Papina, Erastov, et al., 1981; ALS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
5.21247.AStephenson and Malanowski, 1987Based on data from 206. to 262. K.; AC
4.83313.AStephenson and Malanowski, 1987Based on data from 298. to 379. K.; AC
5.19248.N/AMcCullough, Person, et al., 1951Based on data from 206. to 263. K.; AC
5.23235.N/AHeisig and Hurd, 1933Based on data from 195. to 250. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
206.33 to 262.284.02065850.498-33.246Oliver, Grisard, et al., 1951Coefficents calculated by NIST from author's data.

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
1.262118.3Golovanova and Kolesov, 1984, 2DH
1.3271115.0Oliver, Grisard, et al., 1951DH
1.33115.Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
10.7118.3Golovanova and Kolesov, 1984, 2DH
11.54115.0Oliver, Grisard, et al., 1951DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Lacher and Park, 1950
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 10170
Instrument Beckman DU
Melting point - 158
Boiling point - 27.8

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, UV/Visible spectrum, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Erastov and Kolesov, 1982
Erastov, P.A.; Kolesov, V.P., Enthalpy of formation of trifluorochloroethene, J. Chem. Thermodyn., 1982, 14, 103-106. [all data]

Erastov, Kolesov, et al., 1981
Erastov, P.A.; Kolesov, V.P.; Dityateva, L.N.; Golovanova, Yu.G., The enthalpy of formation of 1,1,2-trifluoro-1,2,2-trichloroethane, J. Chem. Thermodyn., 1981, 13, 663-669. [all data]

Papina, Erastov, et al., 1981
Papina, T.S.; Erastov, P.A.; Kolesov, V.P., The enthalpies of formation of 1,1,1-trifluoro-2-chloro-2-bromoethane and 1,1,2-trifluoro-2-chloro-1-bromoethane, J. Chem. Thermodyn., 1981, 13, 683-689. [all data]

Oliver, Grisard, et al., 1951
Oliver, G.D.; Grisard, J.W.; Cunningham, C.W., Thermodynamic properties and P-V-T relations of chlorotrifluoroethylene, J. Am. Chem. Soc., 1951, 73, 5719-5722. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Golovanova and Kolesov, 1984
Golovanova, Y.G.; Kolesov, V.P., Enthalpies of melting, melting temperatures, and cryoscopic constants of some haloorganic compounds, Vestn. Mosk. Univ., Ser. 2: Khim., 1984, 25, 244. [all data]

Oliver, Grisard, et al., 1951, 2
Oliver, G.D.; Grisard, J.W.; Cunningham, C.W., Thermodynamic Properties and P-V-T Relations of Chlorotrifluoroethylene., J. Am. Chem. Soc., 1951, 73, 5719-22. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

McCullough, Person, et al., 1951
McCullough, J.P.; Person, W.B.; Spitzer, Ralph, The Heats of Vaporization and Vapor Heat Capacities of Some Dimethylcyclohexanes 1, J. Am. Chem. Soc., 1951, 73, 9, 4069-4071, https://doi.org/10.1021/ja01153a003 . [all data]

Heisig and Hurd, 1933
Heisig, G.B.; Hurd, Charles D., Vapor Pressure and Boiling Point of Pure Methylacetylene *, J. Am. Chem. Soc., 1933, 55, 8, 3485-3487, https://doi.org/10.1021/ja01335a083 . [all data]

Golovanova and Kolesov, 1984, 2
Golovanova, Yu.G.; Kolesov, V.P., Enthalpies of melting, melting temperatures, and cryoscopic constants of some haloorganic compounds, Vestn. Mosk Univ., Ser. 2: Khim., 1984, 25(3), 244-248. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Lacher and Park, 1950
Lacher, J.R.; Park, J.D., J. Am. Chem. Soc., 1950, 72, 5486. [all data]


Notes

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