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Ethane, 1,1,2,2-tetrachloro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
BS - Robert L. Brown and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil419.3 ± 0.3KAVGN/AAverage of 19 out of 20 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus229.7KN/ATimmermans, 1927Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
Ttriple230.8KN/AKosarukina, Kolesov, et al., 1982Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC
Ttriple230.3KN/AKosarukina, Kolesov, et al., 1982Crystal phase 2 phase; Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tc644.5KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Deltavap45.72kJ/molN/AMajer and Svoboda, 1985 
Deltavap45.73 ± 0.09kJ/molReviewManion, 2002weighted average of several measurements plus a correction for non-ideality; DRB
Deltavap45.78 ± 0.16kJ/molCLaynez and Wadso, 1972ALS
Deltavap45.8 ± 0.2kJ/molCLaynez, Wadsö, et al., 1972AC
Deltavap45.2 ± 1.3kJ/molVMathews, 1926Reanalyzed by Pedley, Naylor, et al., 1986, Original value = 38.7 ± 0.3 kJ/mol; ALS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
37.64419.4N/AMajer and Svoboda, 1985 
42.5358.EBTeodorescu, Barhala, et al., 2006Based on data from 343. - 418. K.; AC
40.4392.AStephenson and Malanowski, 1987Based on data from 377. - 419. K.; AC
41.9343.AStephenson and Malanowski, 1987Based on data from 328. - 464. K. See also Dykyj, 1970.; AC
40.8394.N/ACastellari, Comelli, et al., 1984Based on data from 371. - 419. K.; AC
40.1398.N/ASundaram and Viswanath, 1978Based on data from 377. - 418. K.; AC
39.415.N/ARao and Viswanath, 1977AC
47.7313.N/AMatthews, Sumner, et al., 1950Based on data from 298. - 403. K.; AC
45.7319.N/ANelson, 1930Based on data from 304. - 419. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
298. - 403.3.21563959.602-123.372Matthews, Sumner, et al., 1950, 2Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
9.17230.8Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
2.62207.3Domalski and Hearing, 1996CAL
39.74230.8
1.74204.8
41.5230.3

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.544207.3crystaline, IIcrystaline, IKosarukina, Kolesov, et al., 1982, 2DH
9.172230.8crystaline, IliquidKosarukina, Kolesov, et al., 1982, 2DH
0.356204.8crystaline, IIcrystaline, IKosarukina, Kolesov, et al., 1982, 2DH
9.521230.3crystaline, IIliquidKosarukina, Kolesov, et al., 1982, 2DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
2.62207.3crystaline, IIcrystaline, IKosarukina, Kolesov, et al., 1982, 2DH
39.79230.8crystaline, IliquidKosarukina, Kolesov, et al., 1982, 2DH
1.74204.8crystaline, IIcrystaline, IKosarukina, Kolesov, et al., 1982, 2DH
41.51230.3crystaline, IIliquidKosarukina, Kolesov, et al., 1982, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Timmermans, 1927
Timmermans, J., The Melting Point of Organic Substances, Bull. Soc. Chim. Belg., 1927, 36, 502. [all data]

Kosarukina, Kolesov, et al., 1982
Kosarukina, E.A.; Kolesov, V.P.; Kuramshina, G.M.; Pentin, Y.A., Heat Capacity and thermodynamic functions and polymorphism of 1,1,2,2-tetrachloroethane in the 8 to 300 K range, Termodin. Org. Soedin., 1982, 1982, 11. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Manion, 2002
Manion, J.A., Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons, J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703 . [all data]

Laynez and Wadso, 1972
Laynez, J.; Wadso, I., Enthalpies of vaporization of organic compounds. IX. Some halogen substituted hydrocarbons and esters, Acta Chem. Scand., 1972, 26, 3148. [all data]

Laynez, Wadsö, et al., 1972
Laynez, José; Wadsö, Ingemar; Haug, Arne; Songstad, J.; Pilotti, Åke, Enthalpies of Vaporization of Organic Compounds. IX. Some Halogen Substituted Hydrocarbons and Esters., Acta Chem. Scand., 1972, 26, 3148-3152, https://doi.org/10.3891/acta.chem.scand.26-3148 . [all data]

Mathews, 1926
Mathews, J.H., The accurate measurement of heats of vaporization of liquids, J. Am. Chem. Soc., 1926, 48, 562-576. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Teodorescu, Barhala, et al., 2006
Teodorescu, Mariana; Barhala, Alexandru; Dragoescu, Dana, Isothermal (vapour+liquid) equilibria for the binary (cyclopentanone or cyclohexanone with 1,1,2,2-tetrachloroethane) systems at temperatures of (343.15, 353.15, and 363.15)K, The Journal of Chemical Thermodynamics, 2006, 38, 11, 1432-1437, https://doi.org/10.1016/j.jct.2006.01.010 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1970
Dykyj, J., Petrochemica, 1970, 10, 2, 51. [all data]

Castellari, Comelli, et al., 1984
Castellari, Carlo; Comelli, Fabio; Francesconi, Romolo, Vapor-liquid equilibria in binary systems containing 1,3-dioxolane at isobaric conditions. 4. Binary mixtures of 1,3-dioxolane with 1,4-dioxane and 1,1,2,2-tetrachloroethane, J. Chem. Eng. Data, 1984, 29, 2, 126-128, https://doi.org/10.1021/je00036a008 . [all data]

Sundaram and Viswanath, 1978
Sundaram, S.; Viswanath, D.S., Thermodynamic properties of toluene-1,1,2,2-tetrachloroethane, J. Chem. Eng. Data, 1978, 23, 1, 62-64, https://doi.org/10.1021/je60076a026 . [all data]

Rao and Viswanath, 1977
Rao, Yaddanapudi J.; Viswanath, Dabir S., Integral isobaric heats of vaporization of benzene-chloroethane systems, J. Chem. Eng. Data, 1977, 22, 1, 36-38, https://doi.org/10.1021/je60072a011 . [all data]

Matthews, Sumner, et al., 1950
Matthews, J.B.; Sumner, J.F.; Moelwyn-Hughes, E.A., The vapour pressures of certain liquids, Trans. Faraday Soc., 1950, 46, 797, https://doi.org/10.1039/tf9504600797 . [all data]

Nelson, 1930
Nelson, O.A., Vapor Pressures of Fumigants, Ind. Eng. Chem., 1930, 22, 9, 971-972, https://doi.org/10.1021/ie50249a020 . [all data]

Matthews, Sumner, et al., 1950, 2
Matthews, J.B.; Sumner, J.F.; Moelwyn-Hughes, E.A., The Vapour Pressures of Certain Liquids, Trans. Faraday Soc., 1950, 46, 797-803, https://doi.org/10.1039/tf9504600797 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Kosarukina, Kolesov, et al., 1982, 2
Kosarukina, E.A.; Kolesov, V.P.; Kuramshina, G.M.; Pentin, Yu.A., Heat capacity and thermodynamic functions and polymorphism of 1,1,2, 2-tetrachloroethane in the 8 to 300 K range, 1982, Termodin. [all data]


Notes

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