2-Propenoic acid

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil412.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil414.8KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus285.7KN/AKarabaev, Saidov, et al., 1985DH
Tfus285.7KN/AKarabaev, Abduzhaminov, et al., 1985Uncertainty assigned by TRC = 0.2 K; TRC
Tfus285.3KN/AAnonymous, 1957Uncertainty assigned by TRC = 0.6 K; TRC
Tfus285.45KN/AMoureu and Boutaric, 1920Uncertainty assigned by TRC = 0.5 K; TRC
Tfus290.KN/ARiiber and Schetelig, 1904Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Tc616.57KN/AD'Souza and Teja, 1987Uncertainty assigned by TRC = 3. K; Ambrose's procedure; TRC
Quantity Value Units Method Reference Comment
Pc51.7417atmN/AD'Souza and Teja, 1987Uncertainty assigned by TRC = 0.987 atm; Ambrose's procedure; TRC
Quantity Value Units Method Reference Comment
Δvap12.7 ± 1.0kcal/molCVan-chin-syan, Kochubei, et al., 1996ALS
Δvap12.7kcal/molN/AVan-chin-syan, Kochubei, et al., 1996DRB
Δvap12.7 ± 1.0kcal/molCVan-Chin-Syan, Kochubei, et al., 1996AC
Δvap13.7kcal/molN/AVilcu and Perisanu, 1980AC
Δvap13.70 ± 0.30kcal/molVVilcu and Perisanu, 1980, 2ALS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
10.8356.AStephenson and Malanowski, 1987Based on data from 341. to 414. K. See also Linek and Wichterle, 1973.; AC
7.82308.N/AGubkov, Fermor, et al., 1964Based on data from 293. to 343. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
293. to 343.2.69036621.275-121.929Gubkov, Fermor, et al., 1964, 2Coefficents calculated by NIST from author's data.

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
2.2729285.7Karabaev, Abduzhaminov, et al., 1985, 2DH
2.667285.5Acree, 1991AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
7.96285.7Karabaev, Abduzhaminov, et al., 1985, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Karabaev, Saidov, et al., 1985
Karabaev, M.; Saidov, A.A.; Abduzhaminov, T.P.; Kenisarin, M.M., Heat capacity and molecular kinetic processes of condensed phase acrylates and methacrylates, Izv. Akad. Nauk UzSSR, Ser. Fiz.-Math., 1985, (6), 51-54. [all data]

Karabaev, Abduzhaminov, et al., 1985
Karabaev, M.K.; Abduzhaminov, T.P.; Kenisarin, M.M.; Saidov, A.A., Thermodynamics of the crystal-liquid phase transition in acrylates and methacrylates., Izv. Akad. Nauk Uzb. SSR Ser., Fiz-Mat. Nauk, 1985, 1985, No. 5, 74-7. [all data]

Anonymous, 1957
Anonymous, R., , Am. Pet. Inst. Res. Proj. 6, Carnegie-Mellon Univ., 1957. [all data]

Moureu and Boutaric, 1920
Moureu, C.; Boutaric, A., Some Physico-Chemical Constants of Acrylic Acid, J. Chim. Phys. Phys.-Chim. Biol., 1920, 18, 348-52. [all data]

Riiber and Schetelig, 1904
Riiber, C.N.; Schetelig, Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1904, 48, 345. [all data]

D'Souza and Teja, 1987
D'Souza, R.; Teja, A.S., The prediction of the vapor pressures of carboxylic acids, Chem. Eng. Commun., 1987, 61, 13. [all data]

Van-chin-syan, Kochubei, et al., 1996
Van-chin-syan, Yu.Ya.; Kochubei, V.V.; Sergeev, V.V.; Raevskii, Yu.A.; Gerasimchuk, S.I.; Kotovich, Kh.Z., Thermodynamic properties of some acids and aldehydes of the acrylic series, Sov. J. Chem. Phys. (Engl. Transl.), 1996, 70, 1789-1794, In original 1932. [all data]

Van-Chin-Syan, Kochubei, et al., 1996
Van-Chin-Syan, Yu.Ya.; Kochubei, V.V.; Sergeev, V.V.; Raevskii, Yu.A.; Gerasimchuk, S.I.; Kotovich, Kh.Z., Thermodynamic properties of some acrylic-series acids and aldehydes, Zh. Fiz. Khim., 1996, 70, 11, 1932. [all data]

Vilcu and Perisanu, 1980
Vilcu, R.; Perisanu, S., Rev. Roum. Chim., 1980, 25, 619. [all data]

Vilcu and Perisanu, 1980, 2
Vilcu, R.; Perisanu, S., The ideal gas state enthalpies of formation of some monomers, Rev. Roum. Chim., 1980, 25, 619-624. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Linek and Wichterle, 1973
Linek, J.; Wichterle, I., Liquid-vapour equilibrium. LIX. The systems diisopropyl ether-acrylic acid, isopropyl acetate-acrylic acid, acrylic acid-2-ethylhexanol and methyl isobutyl ketone-acrylic acid, Collect. Czech. Chem. Commun., 1973, 38, 7, 1846-1852, https://doi.org/10.1135/cccc19731846 . [all data]

Gubkov, Fermor, et al., 1964
Gubkov, A.N.; Fermor, N.A.; Smirnov, N.I., Zh. Prikl. Khim. (S.-Peterburg), 1964, 37, 2204. [all data]

Gubkov, Fermor, et al., 1964, 2
Gubkov, A.N.; Fermor, N.A.; Smirnov, N.I., Vapor Pressure of Mono-Poly Systems, Zh. Prikl. Khim. (Leningrad), 1964, 37, 2204-2210. [all data]

Karabaev, Abduzhaminov, et al., 1985, 2
Karabaev, M.K.; Abduzhaminov, T.P.; Kenisarin, M.M.; Saidov, A.A., Thermodynamics of the crystal-liquid phase transition in acrylates and methacrylates, Izv. Akad. Nauk Uzb. SSR, Ser. Fiz.-Mat. Nauk, 1985, (5), 74-77. [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]


Notes

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