Acetyl chloride, chloro-

• Formula: C₂H₂Cl₂O
• Molecular weight: 112.943
• IUPAC Standard InChI: InChI=1S/C2H2Cl2O/c3-1-2(4)5/h1H2 Copy

  
• IUPAC Standard InChIKey: VGCXGMAHQTYDJK-UHFFFAOYSA-N Copy
• CAS Registry Number: 79-04-9
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: α-Chloroacetyl chloride; Chloracetyl chloride; Chloroacetic acid chloride; Chloroacetic chloride; Chloroacetyl chloride; Monochloroacetyl chloride; CH2ClCOCl; Chloroethanoyl chloride; Chlorid kyseliny chloroctove; Chlorure de chloracetyle; UN 1752; Acetyl chloride, 2-chloro-
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Normal boiling point
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Gas Chromatography
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
• Options:
  • Switch to SI units

Data at NIST subscription sites:

• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Normal boiling point

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

References

Go To: Top, Normal boiling point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Landor, Landor, et al., 1977
Landor, P.D.; Landor, S.R.; Odyek, O., Allenes: Synthesis of 1,3,50Trienamides as Potential Insecticides by the Wittig Reaction, J. Chem. Soc., 1977, 1977, 93-5. [all data]

Khan and Johnathan, 1969
Khan, A.Y.; Johnathan, N., Rotational Isomerism in Chloroacetyl Halides, J. Chem. Phys., 1969, 50, 1801. [all data]

Pohloudek-Fabini and Schroepl, 1968
Pohloudek-Fabini, R.; Schroepl, E., Aroyl and Acyl Isothiocyanates I. Synthesis of Acyl and Aroylisothicyanates, Pharm. Zentralk., 1968, 107, 277-83. [all data]

Lee, 1966
Lee, J.B., Preparation of Acyl Halides under Very Mild Conditions, J. Am. Chem. Soc., 1966, 88, 3440-1. [all data]

Aroney, Le Fevre, et al., 1965
Aroney, M.J.; Le Fevre, R.J.W.; Singh, A.N., Molecular polarisability dipole moments, molar kerr constants and apparent conformation of certain alpha-substituted carbonyl compounds, J. Chem. Soc., 1965, 1965, 564. [all data]

Briody and Satchell, 1965
Briody, J.M.; Satchell, D.P., J. Chem. Soc., 1965, 1965, 168-75. [all data]

Parrot, Hervien, et al., 1964
Parrot, J.; Hervien, J.; Ursy, Y.; Paty, M., Preparation and Properties of the N-(chloro and bromoacetyl)-piperdines, Bull. Soc. Chim. Fr., 1964, 1964, 1063-9. [all data]

Gross and Gloede, 1963
Gross, H.; Gloede, J., Chem. Ber., 1963, 96, 1387-94. [all data]

Euranto and Kujanpaa, 1961
Euranto, E.; Kujanpaa, T., The Preparation of α-Halo-sec-alkyl Esters of Aliphatic Acids, Acta Chem. Scand., 1961, 15, 1209-14. [all data]

Ol'dekop and Maier, 1960
Ol'dekop, Y.U.; Maier, N.A., Reaction of Acetyl Peroxide with Mercuric Acetate and Some Salts of Inorganic Acids, Zh. Obshch. Khim., 1960, 30, 3472. [all data]

Seryakov, Vaks, et al., 1960
Seryakov, G.V.; Vaks, S.A.; Sidorina, L.S., Phase equilibrium of liquid-vapor in systems formed from titanium tetrachloride with chlorides of mono - and tri - chloroacetic acids, Zh. Obshch. Khim., 1960, 30, 2130-3. [all data]

Slanina and Hennion, 1937
Slanina, S.J.; Hennion, G.F., Reactions of Alkenyl Esters Derived from Alkylacetylenes, J. Am. Chem. Soc., 1937, 59, 855. [all data]

Branch and Nixon, 1936
Branch, G.E.K.; Nixon, A.C., The Rate of Alcoholysis of Acyl Chlorides, J. Am. Chem. Soc., 1936, 58, 2499-2504. [all data]

Notes

Go To: Top, Normal boiling point, References

• Symbols used in this document:
  

  Tboil

  Boiling point

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.