2-Butanone

• Formula: C₄H₈O
• Molecular weight: 72.1057
• IUPAC Standard InChI: InChI=1S/C4H8O/c1-3-4(2)5/h3H2,1-2H3 Copy

  
• IUPAC Standard InChIKey: ZWEHNKRNPOVVGH-UHFFFAOYSA-N Copy
• CAS Registry Number: 78-93-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Butan-2-one; Butanone; Ethyl methyl ketone; Ketone, methyl ethyl; Methyl ethyl ketone; MEK; C2H5COCH3; Acetone, methyl-; Aethylmethylketon; 3-Butanone; Butanone 2; Ethyl methyl cetone; Ethylmethylketon; Ketone, ethyl methyl; Meetco; Methyl acetone; Metiletilchetone; Metyloetyloketon; Rcra waste number U159; UN 1193; 2-Oxobutane; 2-Butanal; 2-butanone (MEK; methyl ethyl ketone); 2-butanone (MEK)
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• Information on this page:
  • Normal boiling point
  • References
  • Notes
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Normal boiling point

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein

References

Go To: Top, Normal boiling point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wisniak, Fishman, et al., 1998
Wisniak, J.; Fishman, E.; Shaulitch, R., Isobaric Vapor-Liquid Equilibria in the Systems 2-Butanone + Heptane and 3-Butanone + Oxolane, J. Chem. Eng. Data, 1998, 43, 537-40. [all data]

Tojo, Ramallo, et al., 1994
Tojo, J.; Ramallo, A.V.; Orge, B., Vapor-Liquid Equilibria for the Ternary System Methyl Ethyl Ketone + Cyclohexane + Heptane at 101.325 kPa, J. Chem. Eng. Data, 1994, 39, 480-2. [all data]

Tanaka, Muramatsu, et al., 1992
Tanaka, H.; Muramatsu, T.; Kato, M., Isobaric Vapor-Liquid Equilibria for Three Binary Systems of 2-Butanone with 3-Methyl-1-butanol, 1-Butanol, or 2-Butanol, J. Chem. Eng. Data, 1992, 37, 164. [all data]

Yoshikawa and Kato, 1991
Yoshikawa, H.; Kato, M., Vapor-liquid equilibria for three binary systems made of methyl ethyl ketone with acetone, methyl acetate, or N-amyl alcohol, J. Chem. Eng. Data, 1991, 36, 57. [all data]

Kato, Yamaguchi, et al., 1990
Kato, M.; Yamaguchi, M.; Yoshikawa, H., Vapor liquid equilibria 100 Kpa for propionic acid and carbon tetrachloride or 2-butanone., J. Chem. Eng. Data, 1990, 35, 85. [all data]

Wisniak and Tamir, 1990
Wisniak, J.; Tamir, A., Isobaric Vapor-Liquid Equilibria in the Systems Propyl Bromide-Methyl Ethyl Ketone, Methyl Ethyl Ketone-o-Xylene, and Vinyl Acetate-Methyl Methacrylate, J. Chem. Eng. Data, 1990, 35, 147. [all data]

Schrodt and Akel, 1989
Schrodt, J.T.; Akel, R.M., Binary Liquid Viscosities and Their Estimation from Classical Solution Thermodynamics, J. Chem. Eng. Data, 1989, 34, 8. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Kailuru and Abburi, 1988
Kailuru, R.; Abburi, K., Isobaric Vapor-Liquid Equilibria of Methyl Ethyl Ketone(1) + o-Dichlorobenzene(2), + Bromobenzene(2), and + Nitrobenzene(2), J. Chem. Eng. Data, 1988, 33, 251. [all data]

Manjeshwar and Aminabhavi, 1988
Manjeshwar, L.S.; Aminabhavi, T.M., Densities and Viscosities of Binary Liquid Mixtures Containing Bromoform at 45 deg C, J. Chem. Eng. Data, 1988, 33, 184-5. [all data]

Rao and Reddy, 1988
Rao, K.P.C.; Reddy, K.S. (see subram k), Viscosities of Trichloroethylene with Ketones and 1,4-Dioxane at 298.15, 308.15, and 318.15 K, J. Chem. Eng. Data, 1988, 33, 130. [all data]

Aminabhavi, Manjeshwar, et al., 1987
Aminabhavi, T.M.; Manjeshwar, L.S.; Balundgi, R.H., Viscosities of Binary Liquid Mixtures, J. Chem. Eng. Data, 1987, 32, 50-2. [all data]

Manjeshwar and Aminabhavi, 1987
Manjeshwar, L.S.; Aminabhavi, T.M., Densities and Viscosities of Binary Liquid Mixtures at 45 deg. C, J. Chem. Eng. Data, 1987, 32, 409-12. [all data]

Gokavi, Raju, et al., 1986
Gokavi, G.S.; Raju, J.R.; Aminabhavi, T.M.; Balundgi, R.H.; Muddapur, M.V., Viscosities and Densities of Binary Liquid Mixtures of Dimethyl Sulfoxide with Chlorobenzene, Pyridine, and Methyl Ethyl Ketone at 25 35, 45, and 55 deg C, J. Chem. Eng. Data, 1986, 31, 15. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Lencka and Wichterle, 1984
Lencka, M.; Wichterle, I., Vapor-liquid equilibrium in the 2-butanone-water system at 101.325 kPa, Fluid Phase Equilib., 1984, 18, 245. [all data]

Wisniak and Tamir, 1982
Wisniak, J.; Tamir, A., Vapor-Liquid Equilibriuim in the System Methyl Ethyl Ketone-p-Xylene, J. Chem. Eng. Data, 1982, 27, 428. [all data]

Subba Rao, Rao, et al., 1979
Subba Rao, D.; Rao, K.V.; Ravi Prasad, A.; Chiranjivi, C., J. Chem. Eng. Data, 1979, 24, 241-4. [all data]

Kal'nitskaya, Komarova, et al., 1977
Kal'nitskaya, A.M.; Komarova, L.F.; Garber, Yu.N., Azeotropic Series of aliphatic Alcohols with Acetate Esters, Zh. Prikl. Khim. (Leningrad), 1977, 50, 1101-5. [all data]

Marinichev and Vasil'eva, 1976
Marinichev, A.N.; Vasil'eva, I.I., Azeotropic Properties of the System Water-Ethyl Alcohol-Methyl Ethyl Ketone-n-Octane, Zh. Prikl. Khim. (Leningrad), 1976, 49, 2065-9. [all data]

Wisniak and Tamir, 1976
Wisniak, J.; Tamir, A., Vapor-Liquid Equilibria of Methyl Ethyl Ketone - Diethyl Ketone, Methyl Ethyl Ketone - Methyl Isobutyl Ketone, and Diethyl Ketone - Methyl Isobutyl Ketone Systems, J. Chem. Eng. Data, 1976, 21, 185-7. [all data]

Geiseler, Quitzsch, et al., 1973
Geiseler, G.; Quitzsch, K.; Hofmann, H.-P.; Pfestorf, R.Z., Z. Phys. Chem. (Leipzig), 1973, 252, 170. [all data]

Miller and Huang, 1972
Miller, K.J.; Huang, H.-S., Vapor-liquid equilibrium for binary systems 2-butanone with 2-butanol, 1- pentanol, and isoamyl alcohol, J. Chem. Eng. Data, 1972, 17, 77-8. [all data]

Matocha and Van Winkle, 1971
Matocha, I.R.; Van Winkle, M., Vapor-liquid equilibria; ternary system methyl ethyl ketone - 2-propanol - water miscible region, J. Chem. Eng. Data, 1971, 16, 61-5. [all data]

Thayumanasundaram and Rao, 1971
Thayumanasundaram, R.; Rao, P.B., Viscosities of Biunary Mixtures of n-Buthyl Acetate-Methyl Ethyl Ketone or Isoamyl Alcohol at 35 deg C, J. Chem. Eng. Data, 1971, 16, 323. [all data]

Muralimohan and Rao, 1967
Muralimohan, S.; Rao, P.B., Ternary Liquid Equilibria of the Water-Phosphoric Acid-1-Butanol, Butyl Acetate, or Methyl Ethyl Ketone Systems at 35 deg. C, J. Chem. Eng. Data, 1967, 12, 494. [all data]

Aristovich, Morachevskii, et al., 1965
Aristovich, V.Yu.; Morachevskii, A.G.; Sabylin, I.I., Zh. Prikl. Khim. (Leningrad), 1965, 38, 2694. [all data]

Grove and Walden, 1965
Grove, E.L.; Walden, G.E., Variation of Dielectric Constant with Temperature for SOme Five- and Six-Carbon Ketones, J. Chem. Eng. Data, 1965, 10, 98. [all data]

Jeffreys, 1963
Jeffreys, G.V., Phase Equilibrium for System Methylethylketone, Cyclohexane, Water, J. Chem. Eng. Data, 1963, 8, 320-323. [all data]

Eubank and Smith, 1962
Eubank, P.T.; Smith, J.M., Enthalpy Data for Polar Compounds, J. Chem. Eng. Data, 1962, 7, 75. [all data]

Noyce and Snyder, 1958
Noyce, D.S.; Snyder, L.R., J. Am. Chem. Soc., 1958, 80, 4033. [all data]

Shenton and Smith, 1958
Shenton, T.; Smith, J.C., Chem. Ind. (London), 1958, 1958, 1510. [all data]

Murphy, Lastovica, et al., 1957
Murphy, N.F.; Lastovica, J.E.; Fallis, J.G., Correlation of Interfacial Tension of Two-Phase Three-Component Systems, Ind. Eng. Chem., 1957, 49, 1035. [all data]

Rao and Rao, 1957
Rao, M.R.; Rao, C.V., Ternary Liquid Equilibriums IV. Various Systems, J. Appl. Chem., 1957, 7, 659. [all data]

Fitzpatrick and Gettler, 1956
Fitzpatrick, F.W.; Gettler, J.D., J. Am. Chem. Soc., 1956, 78, 530. [all data]

Hatch, 1955
Hatch, L.F., Hydrocarbon Process., 1955, 34, 4, 160. [all data]

Doolittle, 1954
Doolittle, A.K., The Technology of Solvents and Plasticizers, Wiley-Inter- science, New York, 1954. [all data]

Kishimoto and Nomoto, 1954
Kishimoto, T.; Nomoto, O., J. Phys. Soc. Jpn., 1954, 9, 66. [all data]

Hellwig and Van Winkle, 1953
Hellwig, L.R.; Van Winkle, M., Vapour-liquid equilibria for ethyl alcohol binary systems., Ind. Eng. Chem., 1953, 45, 624. [all data]

Cook, 1952
Cook, N.C., , Unpublished, Final Rep. Stand. Proj. on Oxygenated Compounds, Penn. State Univ., College Park, PA, 1952. [all data]

Hill and Van Winkle, 1952
Hill, W.D.; Van Winkle, M., Vapor-liquid equilibria in methanol binary systems methanol + methyl ethyl ketone, methanol + methyl propyl ketone, methanol + methyl isobutyl ketone, Ind. Eng. Chem., 1952, 44, 208-10. [all data]

Othmer, Chudgar, et al., 1952
Othmer, D.F.; Chudgar, M.M.; Levy, S.L., Composition of vapors from boiling binary solutions: binary and ternary systems of acetone, methyl ethyl ketone, and water, Ind. Eng. Chem., 1952, 44, 1872-81. [all data]

Amick, Weiss, et al., 1951
Amick, E.H.; Weiss, M.A.; Kirshenbaum, M.S., System Methyl Ethyl Ketone-sec-Butyl Alcohol. Vapor-Liquid Equilibria, Ind. Eng. Chem., 1951, 43, 969. [all data]

Elderfield and McCarthy, 1951
Elderfield, R.C.; McCarthy, J.R., The reaction of o-phenylenediamines with carbonyl compounds: II aliphatic ketones, J. Am. Chem. Soc., 1951, 73, 975. [all data]

Randall and McKenna, 1951
Randall, M.; McKenna, F.E., The system methyl ethyl ketone + water below 0 c, J. Am. Chem. Soc., 1951, 73, 4859-61. [all data]

Hauser and Humphlett, 1950
Hauser, C.R.; Humphlett, W.J., J. Org. Chem., 1950, 15, 359. [all data]

Holub and Bigelow, 1950
Holub, R.; Bigelow, L.A., J. Am. Chem. Soc., 1950, 72, 4879. [all data]

Dreisbach and Martin, 1949
Dreisbach, R.R.; Martin, R.A., Physical Data on Some Organic Compounds, Ind. Eng. Chem., 1949, 41, 2875-8. [all data]

Lecat, 1949
Lecat, M., Tables Azeotropiques, Vol. 1, 10th ed., Brussels, Belgium, 1949. [all data]

Schuerch and Huntress, 1949
Schuerch, C.; Huntress, E.H., The Schmidt Reaction II. A New Rearangement Obseved during Degradation of Triethylacetic Acid, J. Am. Chem. Soc., 1949, 71, 2238. [all data]

Dashkevich, 1948
Dashkevich, B.N., Production of r-methylketones from carbomethylene, Zh. Obshch. Khim., 1948, 18, 205. [all data]

Kharasch, McBay, et al., 1948
Kharasch, M.S.; McBay, H.C.; Urry, W.H., J. Am. Chem. Soc., 1948, 70, 1269. [all data]

Bourns and Nicholls, 1947
Bourns, A.N.; Nicholls, R.V.V., The catalytic action of aluminum silicates: I the dehydration of butanediol-2,3 and butanone-2 over activated modern bentonite, Can. J. Res., Sect. B, 1947, 25, 80. [all data]

Lecat, 1947
Lecat, M., Orthobaric Azeotropes of Sulfides, Bull. Cl. Sci., Acad. R. Belg., 1947, 33, 160-82. [all data]

Cubberley and Mueller, 1946
Cubberley, A.H.; Mueller, M.B., Equilibrium Studies on the Dehydrogenation of Primary and Secondary Alcohls I. 2-Butanol, 2-Octanol, Cyclopentanol and Benzyl Alcohol, J. Am. Chem. Soc., 1946, 68, 1149. [all data]

Rabjohn and Rogier, 1946
Rabjohn, N.; Rogier, E.R., The vapor-phase chlorination of aliphatic ketones, J. Org. Chem., 1946, 11, 781. [all data]

Platt, Rusoff, et al., 1943
Platt, J.R.; Rusoff, I.I.; Klevens, H.B., J. Chem. Phys., 1943, 11, 535. [all data]

Boeke and Hanewald, 1942
Boeke, J.; Hanewald, K.H., Specific gravity-composition, boiling point-composition and vapour-liquid equilibria relations for the systems methyl ethyl ketone - water and sec butanol - water, Recl. Trav. Chim. Pays-Bas, 1942, 61, 881. [all data]

Ewell and Welch, 1941
Ewell, R.H.; Welch, L.M., Maximum Boiling Mixtures of chloroparaffins with Donor Liquids, J. Am. Chem. Soc., 1941, 63, 2475. [all data]

Paul, 1941
Paul, R., Bull. Soc. Chim. Fr., 1941, 8, 507. [all data]

Ginnings, Plonk, et al., 1940
Ginnings, P.M.; Plonk, D.; Carter, E., Aqueous Solubilities of Some Aliphatic Ketones, J. Am. Chem. Soc., 1940, 62, 1923-1924. [all data]

Schaad and Ipatieff, 1940
Schaad, R.E.; Ipatieff, V.N., Catalytic Hydration of Acetylene and Some Alkylacetylenes, J. Am. Chem. Soc., 1940, 62, 178. [all data]

Bennewitz and Rossner, 1938
Bennewitz, K.; Rossner, W., The molar heat of organic vapors, Z. Phys. Chem., Abt. B, 1938, 39, 126. [all data]

Dolliver, Gresham, et al., 1938
Dolliver, M.A.; Gresham, T.L.; Kistiakowsky, G.B.; Smith, E.A.; Vaughan, W.E., Heats of Organic Reactions VI. Heats of Hydrogenation of Some Oxygen- Containing Compounds, J. Am. Chem. Soc., 1938, 60, 440. [all data]

Gilman and Nelson, 1936
Gilman, H.; Nelson, J.F., Recl. Trav. Chim. Pays-Bas, 1936, 55, 518. [all data]

Felsing, Shofner, et al., 1934
Felsing, W.A.; Shofner, L.; Garlock, N.B., Some Physical Constants of Methyl Ethyl Ketone and an Investigation of its Addition Compound with Sodium Iodide Dihydrate, J. Am. Chem. Soc., 1934, 56, 2252. [all data]

Kohlraush and Koppl, 1934
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Pfeiffer and Adkins, 1931
Pfeiffer, G.J.; Adkins, H., The Relation of the Structure of Ketones to Their Reactivity and Affinity in Acetal Formation II., J. Am. Chem. Soc., 1931, 53, 1043. [all data]

Carswell and Adkins, 1928
Carswell, H.E.; Adkins, H., The Relation of the Structure of Ketones to their Reactivity and Affinity in Acetal Formation, J. Am. Chem. Soc., 1928, 50, 235. [all data]

Grignard and Fluchaire, 1928
Grignard, V.; Fluchaire, M., Suiz les proprietetes condensantes des alcoolates magnesiens mixtures, Ann. Chim. (Paris), 1928, 9, 5. [all data]

Timmermans and Martin, 1928
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Suida and Poll, 1927
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Lecat, 1926
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Mathews, 1926
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Bonino, 1925
Bonino, G.B., Gazz. Chim. Ital., 1925, 55, 335. [all data]

Lochte, 1924
Lochte, H.L., Ind. Eng. Chem., 1924, 16, 956. [all data]

Grimm and Patrick, 1923
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Pringsheim and Leibowitz, 1923
Pringsheim; Leibowitz, Chem. Ber., 1923, 56, 2034. [all data]

Pariselle and Simon, 1921
Pariselle, M.; Simon, L.J., C. R. Hebd. Seances Acad. Sci., 1921, 173, 86. [all data]

Michael, 1919
Michael, A., J. Am. Chem. Soc., 1919, 41, 393. [all data]

Pickard and Kenyon, 1913
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Timmermans, 1911
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Timmermans, 1910
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Sabatier and Mailhe, 1909
Sabatier, P.; Mailhe, A., New Applications of the General Method of Hydrogenation with Various Metals, Ann. Chim. Phys., 1909, 16, 70. [all data]

Guttman, 1907
Guttman, L.F., The determination of melting points at low temperatures: II., J. Am. Chem. Soc., 1907, 29, 345-9. [all data]

Sabatier and Senderens, 1903
Sabatier, P.; Senderens, J.B., C. R. Hebd. Seances Acad. Sci., 1903, 137, 302. [all data]

Louguinine, 1898
Louguinine, W., Study of Latent Heats of Vaporizaion of Some Liquids, Ann. Chim. Phys., 1898, 13, 289-377. [all data]

Grimm, 1871
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Frankland and Duppa, 1866
Frankland, E.; Duppa, B.F., Justus Liebigs Ann. Chem., 1866, 138, 328. [all data]

Notes

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• Symbols used in this document:
  

  Tboil

  Boiling point

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