Propanenitrile, 2,2'-azobis[2-methyl-

• Formula: C₈H₁₂N₄
• Molecular weight: 164.2077
• IUPAC Standard InChI: InChI=1S/C8H12N4/c1-7(2,5-9)11-12-8(3,4)6-10/h1-4H3 Copy

  
• IUPAC Standard InChIKey: OZAIFHULBGXAKX-UHFFFAOYSA-N Copy
• CAS Registry Number: 78-67-1
• Chemical structure:
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• Other names: Propionitrile, 2,2'-azobis[2-methyl-; α,α'-Azobis[isobutyronitrile]; α,α'-Azodiisobutyric acid dinitrile; α,α'-Azodi(isobutyronitrile); Aceto AZIB; Azobis[isobutyronitrile]; Azodi(isobutyronitrile); AIBN; AIVN; AZDH; Genitron; Pianofor An; Porofor N; Porophor N; Vazo; Vazo 64; 2,2'-Azobis[isobutyronitrile]; 2,2'-Azobis[2-methylpropionitrile]; 2,2'-Azodi(isobutyronitrile); 2,2'-Dimethyl-2,2'-azodipropionitrile; 2,2'-Azobis-(2-methylpropanenitrile); α,α-Azobisisobutyronitrile; α,α'-Azobis(isobutylonitrile); α,α'-Azodisobutyric acid dinitrile; Azobisisobutylonitrile; ChKhZ 57; Porofor 57; 2,2'-Dicyano-2,2'-azopropane; Poly-zole AZDN; N,N'-Bis(2-cyano-2-propyl)diazene; Genitron AZDN-FF; Genitron AZDN; 2,2-Azodiisobutyronitrile; Azodiisobutyrodinitrile; V-60; Alpha,alpha'-azo-di-iso-butyronitrile; Propanenitrile, 2,2'-(1,2-diazenediyl)bis(2-methyl-; NSC 1496; 2,2-azobis[2-methyl-]-propanenitrile (AZDH); 2,2'-dimethyl-2,2'-azodipropiononitrile
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• Information on this page:
  • Condensed phase thermochemistry data
  • Phase change data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • References
  • Notes
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Enthalpy of sublimation

IR Spectrum

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Data compiled by: Coblentz Society, Inc.

• SOLID (OIL MULL); Not specified, most likely a prism, grating, or hybrid spectrometer.; DIGITIZED BY NIST FROM HARD COPY; 4 cm^-1 resolution

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

• gas; HP-GC/MS/IRD

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedeva, Gutner, et al., 1984
Lebedeva, N.D.; Gutner, N.M.; Katin, Yu.A.; Kozlova, N.M.; Kiseleva, N.N.; Makhina, E.F.; Dobychin, S.L., Thermochemical study of bis-hydroxyethylpiperazine, N,N-dimethylpropylenediamine, and 2,2-azodiisobutyrodinitrile, J. Appl. Chem. USSR, 1984, 57, 2118-2122. [all data]

McEwan and Rigg, 1951
McEwan, W.S.; Rigg, M.W., The heats of combustion of compounds containing the tetrazole ring, J. Am. Chem. Soc., 1951, 73, 4725-4727. [all data]

Reed, 1960
Reed, R.A., New blowing agents for foaming plastics, British Plastics, 1960, 33, 468-472. [all data]

Lebedeva, Gutner, et al., 1984, 2
Lebedeva, N.D.; Gutner, N.M.; Katin, Yu.A.; Kozlova, N.M.; Kiseleva, N.N.; Machinya, E.F.; Dobychin, S.L.; Thermochemical study of bis(hydroxyethyl)piperazine, N., N-dimethylpropylenediamine and 2,2-azodiisobutyric acid dinitrile, Zhur. Prikl. Khim. (Leningrad), 1984, 57(10), 2297-2301. [all data]

Lebedeva, Ryadnenko, et al., 1981
Lebedeva, N.D.; Ryadnenko, V.L.; Kozlova, N.M.; Karpenko, N.A.; Stepanov, V.B., Heat capacities of some organic compounds, 1981, Termodinam. [all data]

Notes

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• Symbols used in this document:
  

  Cp,solid	Constant pressure heat capacity of solid
  Tfus	Fusion (melting) point
  ΔcH°solid	Enthalpy of combustion of solid at standard conditions
  ΔfH°solid	Enthalpy of formation of solid at standard conditions
  ΔsubH	Enthalpy of sublimation

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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