Silane, diethoxydimethyl-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, IR Spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil387.KN/APCR Inc., 1990BS
Quantity Value Units Method Reference Comment
Δvap10.3 ± 0.2kcal/molCVoronkov, Baryshok, et al., 1988AC
Δvap10.3 ± 0.07kcal/molEBKlyuchnikov, Danilova, et al., 1985AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
10.3269.Stull, 1947Based on data from 254. to 386. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A B C Reference Comment
254.1 to 386.74.435261490.127-50.429Stull, 1947Coefficents calculated by NIST from author's data.

IR Spectrum

Go To: Top, Phase change data, Gas Chromatography, References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Gas Chromatography

Go To: Top, Phase change data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
PackedApiezon M160.678.Peetre, Ellren, et al., 1985Chromosorb G; Column length: 3. m

Normal alkane RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
PackedApieson M160.678.Ellren, Peetre, et al., 1974Chromosorb G AW DMCS (80-100 mesh)

References

Go To: Top, Phase change data, IR Spectrum, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Voronkov, Baryshok, et al., 1988
Voronkov, M.G.; Baryshok, V.P.; Klyuchnikov, V.A.; Danilova, T.F.; Pepekin, V.I.; Korchagina, A.N.; Khudobin, Yu.I., Thermochemistry of organosilicon compounds, Journal of Organometallic Chemistry, 1988, 345, 1-2, 27-38, https://doi.org/10.1016/0022-328X(88)80231-6 . [all data]

Klyuchnikov, Danilova, et al., 1985
Klyuchnikov, V.A.; Danilova, T.F.; Voronkov, M.G.; D'yakov, V.M., Dokl. Phys. Chem., 1985, 281, 373. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Peetre, Ellren, et al., 1985
Peetre, I.-B.; Ellren, O.; Smith, B.E.F., Gas chromatographic investigation of organometallic compounds and their carbon analogues. VI. Determination, calculation and correlation of Kováts retention indices for alkylalkoxysilanes, J. Chromatogr., 1985, 318, 41-55, https://doi.org/10.1016/S0021-9673(01)90662-4 . [all data]

Ellren, Peetre, et al., 1974
Ellren, O.; Peetre, I.B.; Smith, B.E.F., Gas chromatographic investigation of organometallic compounds and their carbon analogues. V. Use of refractive index in conjunction with Kovats retention index for the identification of organosilicon compounds, J. Chromatogr., 1974, 93, 2, 383-392, https://doi.org/10.1016/S0021-9673(01)85402-9 . [all data]


Notes

Go To: Top, Phase change data, IR Spectrum, Gas Chromatography, References