e-Diazene, bis(bicyclo[2.2.2]oct-1-yl)-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

cis-1-Azobicyclo[2.2.2]octane = e-Diazene, bis(bicyclo[2.2.2]oct-1-yl)-

By formula: C16H26N2 = C16H26N2

Quantity Value Units Method Reference Comment
Δr-6.19 ± 0.16kcal/molKinSchmittel and Ruchardt, 1987solid phase; solvent: Mesitylene

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schmittel and Ruchardt, 1987
Schmittel, M.; Ruchardt, C., Stereoisomerization and homolytic decomposition of cis and trans bridgehead diazenes, J. Am. Chem. Soc., 1987, 109, 2750-2759. [all data]


Notes

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