Tetraethoxymethane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δfgas-206.0 ± 0.50kcal/molCcrMarsh and Mansson, 1985ALS
Δfgas-207.0kcal/molN/ALebedeva, Ryadnenko, et al., 1977Value computed using ΔfHliquid° value of -919.0±1.0 kj/mol from Lebedeva, Ryadnenko, et al., 1977 and ΔvapH° value of 52.9 kj/mol from Marsh and Mansson, 1985.; DRB

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-218.6 ± 0.50kcal/molCcrMarsh and Mansson, 1985 
Δfliquid-219.6 ± 0.3kcal/molCcbLebedeva, Ryadnenko, et al., 1977 
Quantity Value Units Method Reference Comment
Δcliquid-1311.3 ± 0.40kcal/molCcrMarsh and Mansson, 1985Corresponding Δfliquid = -218.4 kcal/mol (simple calculation by NIST; no Washburn corrections)
Δcliquid-1310.0 ± 0.5kcal/molCcbLebedeva, Ryadnenko, et al., 1977Corresponding Δfliquid = -219.6 kcal/mol (simple calculation by NIST; no Washburn corrections)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Marsh and Mansson, 1985
Marsh, K.N.; Mansson, M., Standard molar enthalpies of formation of triethoxymethane and tetraethoxymethane by rotating bomb calorimetry, J. Chem. Thermodyn., 1985, 17, 995-1002. [all data]

Lebedeva, Ryadnenko, et al., 1977
Lebedeva, N.D.; Ryadnenko, V.L.; Gutner, N.M.; Nazarova, L.F.; Kiseleva, N.N.; Aizenshtadt, I.N.; Kirilenko, I.V., Possibility of using additive schemes for estimation of the enthalpies of formation of polyfunctional compounds, J. Anal. Chem. USSR (Engl. Transl.), 1977, 50, 726-729. [all data]


Notes

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