Tetraethoxymethane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δfgas-206.0 ± 0.50kcal/molCcrMarsh and Mansson, 1985ALS
Δfgas-207.0kcal/molN/ALebedeva, Ryadnenko, et al., 1977Value computed using ΔfHliquid° value of -919.0±1.0 kj/mol from Lebedeva, Ryadnenko, et al., 1977 and ΔvapH° value of 52.9 kj/mol from Marsh and Mansson, 1985.; DRB

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil432.7KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Δvap12.63 ± 0.036kcal/molCMarsh and Mansson, 1985ALS
Δvap12.6kcal/molN/AMarsh and Mansson, 1985DRB
Δvap12.6 ± 0.05kcal/molCMarsh and Mansson, 1985AC
Δvap9.7 ± 0.7kcal/molVLebedeva, Ryadnenko, et al., 1977ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Marsh and Mansson, 1985
Marsh, K.N.; Mansson, M., Standard molar enthalpies of formation of triethoxymethane and tetraethoxymethane by rotating bomb calorimetry, J. Chem. Thermodyn., 1985, 17, 995-1002. [all data]

Lebedeva, Ryadnenko, et al., 1977
Lebedeva, N.D.; Ryadnenko, V.L.; Gutner, N.M.; Nazarova, L.F.; Kiseleva, N.N.; Aizenshtadt, I.N.; Kirilenko, I.V., Possibility of using additive schemes for estimation of the enthalpies of formation of polyfunctional compounds, J. Anal. Chem. USSR (Engl. Transl.), 1977, 50, 726-729. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]


Notes

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