Chloridosulfuric acid


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
45.8339.Dykyj, Svoboda, et al., 1999Based on data from 324. to 454. K.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

n-Pentadecanol + Chloridosulfuric acid = Pentadecyl sulfuric acid + Hydrogen chloride

By formula: C15H32O + ClHO3S = C15H32O4S + HCl

Quantity Value Units Method Reference Comment
Δr56. ± 3.kJ/molCmMarkitanova, Barsukov, et al., 1981liquid phase; solvent: Dichloromethane; Sulfation

1-Hexadecanol + Chloridosulfuric acid = C16H34O4S + Hydrogen chloride

By formula: C16H34O + ClHO3S = C16H34O4S + HCl

Quantity Value Units Method Reference Comment
Δr57. ± 3.kJ/molCmMarkitanova, Barsukov, et al., 1981liquid phase; solvent: Dichloromethane; Sulfation

1-Butanol + Chloridosulfuric acid = Butyl sulfuric acid + Hydrogen chloride

By formula: C4H10O + ClHO3S = C4H10O4S + HCl

Quantity Value Units Method Reference Comment
Δr58. ± 1.kJ/molCmMarkitanova, Barsukov, et al., 1981liquid phase; solvent: Dichloromethane; Sulfation

1-Undecanol + Chloridosulfuric acid = Undecyl sulfuric acid + Hydrogen chloride

By formula: C11H24O + ClHO3S = C11H24O4S + HCl

Quantity Value Units Method Reference Comment
Δr60. ± 3.kJ/molCmMarkitanova, Barsukov, et al., 1981liquid phase; solvent: Dichloromethane; Sulfation

1-Octanol + Chloridosulfuric acid = C8H18O4S + Hydrogen chloride

By formula: C8H18O + ClHO3S = C8H18O4S + HCl

Quantity Value Units Method Reference Comment
Δr55. ± 1.kJ/molCmMarkitanova, Barsukov, et al., 1981liquid phase; solvent: Dichloromethane; Sulfation

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Spectrum

A digitized version of this spectrum is not currently available.

Additional Data

View scan of original (hardcopy) spectrum.

Owner COBLENTZ SOCIETY
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Source reference COBLENTZ NO. 1258
Date Not specified, most likely prior to 1970
Instrument Not specified, most likely a prism, grating, or hybrid spectrometer.
Data processing (NO SPECTRUM, ONLY SCANNED IMAGE IS AVAILABLE)

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Markitanova, Barsukov, et al., 1981
Markitanova, L.I.; Barsukov, I.I.; Passet, B.V., Determination of heat of sulfation by calorimetric titration, J. Gen. Chem. USSR, 1981, 51, 1286-1289. [all data]


Notes

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