cerium triiodide


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub70.5 ± 2.4kcal/molTEVillani, Brunetti, et al., 2000Based on data from 910. to 1031. K.

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Clustering reactions

Iodide + CeI3 = (Iodide • CeI3)

By formula: I- + CeI3 = (I- • CeI3)

Quantity Value Units Method Reference Comment
Δr67.0 ± 8.0kcal/molTDEqChantry, 1976gas phase; B,M
Quantity Value Units Method Reference Comment
Δr28.cal/mol*KMSChantry, 1976gas phase; heated collision chamber; M
Quantity Value Units Method Reference Comment
Δr59. ± 10.kcal/molTDEqChantry, 1976gas phase; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Villani, Brunetti, et al., 2000
Villani, Anna Rita; Brunetti, Bruno; Piacente, Vincenzo, Vapor Pressure and Enthalpies of Vaporization of Cerium Trichloride, Tribromide, and Triiodide, J. Chem. Eng. Data, 2000, 45, 5, 823-828, https://doi.org/10.1021/je000035e . [all data]

Chantry, 1976
Chantry, P.J., Negative Ion Formation in Cerium Triiodide, J. Chem. Phys., 1976, 65, 11, 4412, https://doi.org/10.1063/1.432992 . [all data]


Notes

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