calcium fluoride


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-784.50kJ/molReviewChase, 1998Data last reviewed in December, 1968
Quantity Value Units Method Reference Comment
gas,1 bar273.77J/mol*KReviewChase, 1998Data last reviewed in December, 1968

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 4000. to 6000.
A 57.35762
B 0.717841
C -0.194217
D 0.016557
E -0.571350
F -803.5498
G 339.7609
H -784.5000
ReferenceChase, 1998
Comment Data last reviewed in December, 1968

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-1186.07kJ/molReviewChase, 1998Data last reviewed in December, 1968
Quantity Value Units Method Reference Comment
liquid,1 bar92.60J/mol*KReviewChase, 1998Data last reviewed in December, 1968
Quantity Value Units Method Reference Comment
Δfsolid-1225.91kJ/molReviewChase, 1998Data last reviewed in December, 1968
Quantity Value Units Method Reference Comment
solid68.63J/mol*KReviewChase, 1998Data last reviewed in December, 1968

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1691. to 4000.
A 99.91434
B -6.798332×10-9
C 2.346242×10-9
D -2.687513×10-10
E -2.188241×10-9
F -1229.807
G 187.1574
H -1186.068
ReferenceChase, 1998
Comment Data last reviewed in December, 1968

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1424.1424. to 1691.
A 89.88404108.0564
B -46.1202310.39532
C 65.277930.022966
D -17.86271-0.002862
E -1.139438-0.028030
F -1255.008-1288.191
G 182.0057147.7006
H -1225.912-1225.912
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1968 Data last reviewed in December, 1968

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

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