Cesium iodide


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub191.1kJ/molMSViswanathan and Hilpert, 2010See also Pankajavalli, Mallika, et al., 1998.
Δsub195.6kJ/molGSPankajavalli, Mallika, et al., 1998 
Δsub193.1kJ/molTCordfunke, 1986See also Pankajavalli, Mallika, et al., 1998.
Δsub193.1kJ/molTVenugopal, Prasad, et al., 1985See also Pankajavalli, Mallika, et al., 1998.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Iodide + Cesium iodide = (Iodide • Cesium iodide)

By formula: I- + CsI = (I- • CsI)

Quantity Value Units Method Reference Comment
Δr141.00 ± 0.21kJ/molN/AWang, Wang, et al., 2010gas phase
Δr151. ± 5.4kJ/molN/AGusarov, Gorokhov, et al., 1979gas phase; value altered from reference due to conversion from electron convention to ion convention

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Iodide + Cesium iodide = (Iodide • Cesium iodide)

By formula: I- + CsI = (I- • CsI)

Quantity Value Units Method Reference Comment
Δr141.00 ± 0.21kJ/molN/AWang, Wang, et al., 2010gas phase
Δr151. ± 5.4kJ/molN/AGusarov, Gorokhov, et al., 1979gas phase; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Viswanathan and Hilpert, 2010
Viswanathan, R.; Hilpert, K., Mass Spectrometric Study of the Vaporization of Cesium Iodide and Thermochemistry of (CsI)2(g) and (CsI)3(g), Berichte der Bunsengesellschaft für physikalische Chemie, 2010, 88, 2, 125-131, https://doi.org/10.1002/bbpc.19840880210 . [all data]

Pankajavalli, Mallika, et al., 1998
Pankajavalli, R.; Mallika, C.; Sreedharan, O.M.; Premila, M.; Gopalan, Padma, Vapour pressure of C60 by a transpiration method using a horizontal thermobalance, Thermochimica Acta, 1998, 316, 1, 101-108, https://doi.org/10.1016/S0040-6031(98)00304-9 . [all data]

Cordfunke, 1986
Cordfunke, E.H.P., Thermodynamic properties of CSI. II. vapour pressures and thermochemical properties of CsI(g) and Cs2I2(g), Thermochimica Acta, 1986, 108, 45-55, https://doi.org/10.1016/0040-6031(86)85076-6 . [all data]

Venugopal, Prasad, et al., 1985
Venugopal, V.; Prasad, R.; Sood, D.D., Vaporisation thermodynamics of caesium iodide and caesium chromate, Journal of Nuclear Materials, 1985, 130, 115-121, https://doi.org/10.1016/0022-3115(85)90300-9 . [all data]

Wang, Wang, et al., 2010
Wang, Y.L.; Wang, X.B.; Xing, X.P.; Wei, F.; Li, J.; Wang, L.S., Photoelectron Imaging and Spectroscopy of MI2- (M = Cs, Cu, Au): Evolution from Ionic to Covalent Bonding, J. Phys. Chem. A, 2010, 114, 42, 11244-11251, https://doi.org/10.1021/jp103173d . [all data]

Gusarov, Gorokhov, et al., 1979
Gusarov, A.V.; Gorokhov, L.N.; Pyatenko, A.T.; Sidorova, I.V., Negative ions in the vapors of inorganic compounds, Adv. Mass Spectrom., 1979, 8, 262. [all data]


Notes

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