bismuth trichloride


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
503.7 to 710.65.669684143.04619.221Yanai, Watanabe, et al., 1973Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
124.7371. to 468.MECubicciotti, 1966See also Darnell and Yosim, 1959.; AC
118.8 ± 0.4420.MEDarnell and Yosim, 1959Based on data from 371. to 468. K.; AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + BiCl3 = BiCl4-

By formula: Cl- + BiCl3 = BiCl4-

Quantity Value Units Method Reference Comment
Δr153. ± 15.kJ/molCIDTWalker, Check, et al., 2002gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + BiCl3 = BiCl4-

By formula: Cl- + BiCl3 = BiCl4-

Quantity Value Units Method Reference Comment
Δr153. ± 15.kJ/molCIDTWalker, Check, et al., 2002gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Yanai, Watanabe, et al., 1973
Yanai, M.; Watanabe, F.; Saeki, Y., The Vapor Pressure of Bismuth Trichloride, J. Less-Common Met., 1973, 33, 3, 387-389, https://doi.org/10.1016/0022-5088(73)90192-6 . [all data]

Cubicciotti, 1966
Cubicciotti, Daniel, A New Σ-Plot Treatment of Equilibrium Data and Its Application to the Vaporization of Bismuth Chloride 1, J. Phys. Chem., 1966, 70, 7, 2410-2413, https://doi.org/10.1021/j100879a504 . [all data]

Darnell and Yosim, 1959
Darnell, A.J.; Yosim, S.J., Some Thermodynamic Properties of Solid Bismuth Chloride, J. Phys. Chem., 1959, 63, 11, 1813-1815, https://doi.org/10.1021/j150581a005 . [all data]

Walker, Check, et al., 2002
Walker, B.W.; Check, C.E.; Lobring, K.C.; Pommerening, C.A.; Sunderlin, L.S., The Thermochemistry of Group 15 Tetrachloride Anions, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 469, https://doi.org/10.1016/S1044-0305(02)00369-0 . [all data]


Notes

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