pentafluoroarsorane


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
155.3 to 220.42.87778369.088-91.799Stull, 1947Coefficents calculated by NIST from author's data.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Fluorine anion + pentafluoroarsorane = (Fluorine anion • pentafluoroarsorane)

By formula: F- + AsF5 = (F- • AsF5)

Quantity Value Units Method Reference Comment
Δr>85. ± 10.kcal/molN/AHaartz and McDaniel, 1973gas phase; Greater than BCl3
Quantity Value Units Method Reference Comment
Δr>74. ± 10.kcal/molIMRBHaartz and McDaniel, 1973gas phase; Greater than BCl3

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Haartz and McDaniel, 1973
Haartz, J.C.; McDaniel, D.H., Fluoride ion affinity of some lewis acids, J. Am. Chem. Soc., 1973, 95, 8562. [all data]


Notes

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