titanium tetrafluoride
- Formula: F4Ti
- Molecular weight: 123.861
- IUPAC Standard InChI: InChI=1S/4FH.Ti/h4*1H;/q;;;;+4/p-4
- IUPAC Standard InChIKey: XROWMBWRMNHXMF-UHFFFAOYSA-J
- CAS Registry Number: 7783-63-3
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Titanium fluoride
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Clustering reactions
+
= (
•
)
By formula: F- + F4Ti = (F- • F4Ti)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 86.3 ± 3.8 | kcal/mol | TDAs | Boltalina, Borshchevskii, et al., 1992 | gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention |
| ΔrH° | 86.0 ± 5.3 | kcal/mol | TDEq | Boltalina, Borshchevskii, et al., 1991 | gas phase; Fluoride Affinity: 30.3 kcal/mol < AlF3 (Data at 0 K); value altered from reference due to conversion from electron convention to ion convention |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N.,
Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase,
Russ. J. Phys. Chem., 1992, 66, 1223. [all data]
Boltalina, Borshchevskii, et al., 1991
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N.; Chepurnykh, V.N.,
Enthalpy of the Formation of TiF5- Anion in a Gas Phase,
Zh. Fiz. Khim. SSSR, 1991, 65, 928. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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