titanium tetrafluoride


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

Fluorine anion + titanium tetrafluoride = (Fluorine anion • titanium tetrafluoride)

By formula: F- + F4Ti = (F- • F4Ti)

Quantity Value Units Method Reference Comment
Δr86.3 ± 3.8kcal/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention
Δr86.0 ± 5.3kcal/molTDEqBoltalina, Borshchevskii, et al., 1991gas phase; Fluoride Affinity: 30.3 kcal/mol < AlF3 (Data at 0 K); value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase, Russ. J. Phys. Chem., 1992, 66, 1223. [all data]

Boltalina, Borshchevskii, et al., 1991
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N.; Chepurnykh, V.N., Enthalpy of the Formation of TiF5- Anion in a Gas Phase, Zh. Fiz. Khim. SSSR, 1991, 65, 928. [all data]


Notes

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