gallium trifluoride
- Formula: F3Ga
- Molecular weight: 126.718
- CAS Registry Number: 7783-51-9
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: AlF4- + F3Ga = (AlF4- • F3Ga)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 48.3 ± 4.2 | kcal/mol | TDEq | Zhuravleva, Nikitin, et al., 1985 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
By formula: F- + F3Ga = (F- • F3Ga)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 110.3 ± 4.1 | kcal/mol | TDAs | Zhuravleva, Nikitin, et al., 1985 | gas phase; Fluoride Affinity: 7.5 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention |
By formula: F4Ga- + F3Ga = F7Ga2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 51.9 ± 4.7 | kcal/mol | TDEq | Zhuravleva, Nikitin, et al., 1985 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zhuravleva, Nikitin, et al., 1985
Zhuravleva, L.V.; Nikitin, M.I.; Sorokin, I.D.; Sidorov, L.N.,
Mass Spectrometric Determination of the Enthalpies of Dissociation of Gaseous Complex Fluorides into Neutral and Charged Particles. VIII. MF-..GaF3 Systems (M=Li, Na, K, Rb, Cs),
Int. J. Mass Spectrom. Ion Proc., 1985, 65, 3, 253, https://doi.org/10.1016/0168-1176(85)87002-6
. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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