gallium trifluoride

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

AlF4- + F3Ga = (AlF4- • F3Ga)

By formula: AlF4- + F3Ga = (AlF4- • F3Ga)

Quantity Value Units Method Reference Comment
Δr48.3 ± 4.2kcal/molTDEqZhuravleva, Nikitin, et al., 1985gas phase; value altered from reference due to conversion from electron convention to ion convention

Fluorine anion + F3Ga = (Fluorine anion • F3Ga)

By formula: F- + F3Ga = (F- • F3Ga)

Quantity Value Units Method Reference Comment
Δr110.3 ± 4.1kcal/molTDAsZhuravleva, Nikitin, et al., 1985gas phase; Fluoride Affinity: 7.5 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention

F4Ga- + F3Ga = F7Ga2-

By formula: F4Ga- + F3Ga = F7Ga2-

Quantity Value Units Method Reference Comment
Δr51.9 ± 4.7kcal/molTDEqZhuravleva, Nikitin, et al., 1985gas phase; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zhuravleva, Nikitin, et al., 1985
Zhuravleva, L.V.; Nikitin, M.I.; Sorokin, I.D.; Sidorov, L.N., Mass Spectrometric Determination of the Enthalpies of Dissociation of Gaseous Complex Fluorides into Neutral and Charged Particles. VIII. MF-..GaF3 Systems (M=Li, Na, K, Rb, Cs), Int. J. Mass Spectrom. Ion Proc., 1985, 65, 3, 253, https://doi.org/10.1016/0168-1176(85)87002-6 . [all data]


Notes

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